期刊
ACS APPLIED ENERGY MATERIALS
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.3c003394354
关键词
polymer solar cells; power conversion efficiency; half-planar-half-twisted small molecules; non-fullerene acceptors; asymmetric molecules
A series of asymmetric acceptor-pi-donor-pi '-acceptor-type (A-pi-D-pi '-A) non-fullerene acceptors (NFAs) were synthesized by linking halogenated ending groups at the 4-position of 3-ethylhexoxythiophene (pi-segment) on one side and at the 5 position of 3-ethylhexoxythiophene (pi'-segment) on the other side. The asymmetrical molecular structure and distinct pi-bridged segments resulted in a half-planar-half twisted backbone configuration. The fluorine and chlorine atoms on h-IEICO-4F and h-IEICO-4Cl exhibited excellent electron-attracting properties, leading to red-shifted absorption and down-shifted molecular energy levels. The J52:h-IEICO-4F device showed superior performance with enhanced exciton dissociation and collection efficiency, suppressed charge recombination, high and balanced charge transport ability, improved morphological properties, and better crystallinity.
A series of asymmetric acceptor-pi-donor-pi '- acceptor-type (A-pi-D-pi '-A) non-fullerene acceptors (NFAs) were designed and synthesized, namely, h-IEICO, h-IEICO-2F, hIEICO-4F, and h-IEICO-4Cl, which were prepared by simultaneously linking halogenated ending groups both at the 4-position of 3-ethylhexoxythiophene (pi-segment) of one side and at the 5 position of 3-ethylhexoxythiophene (pi '-segment) of another side. The asymmetric molecular structure, as well as the radically different steric hindrance caused by the two distinct pi-bridged segments, successfully produced a wondrous half-planar-half twisted backbone configuration. As a result of the special molecular structures of these materials, as well as the excellent electron-attracting properties of the fluorine and chlorine atoms attached to them, h-IEICO-4F and h-IEICO-4Cl are characterized by an absorption red-shift and a down-shifted molecular energy level among all four molecules. The J52:h-IEICO-4F device demonstrated preferable exciton dissociation and collection efficiency, suppressed charge recombination, a high and balanced charge transport ability, superior morphological properties, and better crystallinity, resulting in an efficiency of 11.65%. However, the efficiencies of the J52:h-IEICO-, J52:h-IEICO-2F-, and J52:h-IEICO-4Cl-based solar cells are 5.24, 9.96, and 10.43%, respectively. This work demonstrates the significant influence of the adjusting planarity of the conjugated backbone as well as the fine-tuning of the end-group halogenation substitution on the characteristic regulation and the photovoltaic performances of NFAs for efficient PSCs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据