期刊
NEW JOURNAL OF CHEMISTRY
卷 47, 期 19, 页码 9421-9426出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj05242c
关键词
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An efficient Ir(iii)-catalyzed decarbonylative annulation of salicylaldehydes with cyclohexane-1,3-diones has been achieved via the in situ generated iodonium ylides. The reaction proceeds smoothly under mild and operationally simple conditions, affording a variety of benzofuran derivatives in moderate to high yields with good functional group tolerance. Moreover, the large-scale synthesis and further modification of the products highlight the utility of this protocol.
An efficient Ir(iii)-catalyzed decarbonylative annulation of salicylaldehydes with cyclohexane-1,3-diones has been achieved via the in situ generated iodonium ylides. The reaction proceeds smoothly under mild and operationally simple conditions, affording a variety of benzofuran derivatives in moderate to high yields with good functional group tolerance. Moreover, the large-scale synthesis and further modification of the products highlight the utility of this protocol.
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