期刊
NEW JOURNAL OF CHEMISTRY
卷 47, 期 21, 页码 10061-10069出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3nj00978e
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The researchers synthesized bifunctional electrode materials, ZnMn2O4/rGO, by using a simple hydrothermal route. The composite exhibited a specific surface area of 67.82 m(2) g(-1) and demonstrated bifunctional behavior for both lithium-ion batteries and supercapacitors. It displayed exceptional discharge/charge capacity and maintained stable cycling behavior even after multiple cycles, making it a promising candidate for energy storage applications.
The synthesis of bifunctional electrode materials is of tremendous interest for energy storage applications. A simple hydrothermal route is chosen to develop reduced graphene oxide encapsulated zinc manganite microspheres (ZnMn2O4/rGO). Microspheres with a needle-like surface architecture could be produced by carefully regulating the process parameters during synthesis and post-annealing. The ZnMn2O4/rGO composite exhibited a specific surface area of 67.82 m(2) g(-1). The ZnMn2O4/rGO composite electrode demonstrated bifunctional behavior for both lithium-ion batteries and supercapacitors. As an anode, it displayed exceptional discharge/charge capacity of 1578/1012 mA h g(-1) at a current density of 0.1 A g(-1) and maintained stable cycling behavior even after 300 cycles at a current density of 1 A g(-1). Moreover, it showed excellent capacitive behavior with a specific capacity of 100.5 mA h g(-1) at 1 A g(-1) and maintained a cycling stability of 83% at 2 A g(-1) even after 5000 cycles. Therefore, ZnMn2O4/rGO composites are promising candidates for practical applications in energy storage.
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