期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 42, 页码 6399-6402出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc01542d
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Half a century after the photolytic disproportionation of Lappert's dialkyl stannylene SnR2, R = CH(SiMe3)(2) (1) gave the persistent trivalent radical [SnR3], the characterization of the corresponding Sn(i) product, SnR is now described. It was isolated as the hexastannaprismane Sn6R6 (2), from the reduction of 1 by the Mg(i)-reagent, Mg(BDIDip)(2) (BDI = (DipNCMe)(2)CH, Dip = 2,6-diisopropylphenyl).
Half a century after the photolytic disproportionation of Lappert's dialkyl stannylene SnR2, R = CH(SiMe3)(2) (1) gave the persistent trivalent radical [SnR3], the characterization of the corresponding Sn(i) product, SnR is now described. It was isolated as the hexastannaprismane Sn6R6 (2), from the reduction of 1 by the Mg(i)-reagent, Mg(BDIDip)(2) (BDI = (DipNCMe)(2)CH, Dip = 2,6-diisopropylphenyl).
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