期刊
ORGANIC CHEMISTRY FRONTIERS
卷 10, 期 12, 页码 2949-2954出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3qo00218g
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In this study, the first series of radicals derived from boron-dipyrromethene (DPMBF2)-D-Trip and its heavier analogues (DPMAlI2)-D-Trip and (DPMGaI2)-D-Trip were successfully isolated and structurally characterized. Spectroscopy analysis, X-ray crystallography, and theoretical calculations revealed the increasing delocalization over the dipyrromethene scaffold upon one-electron reduction, with the unpaired electrons mainly delocalized over the dipyrromethene backbone and negligible spin density on the group 13 element centers.
Boron-dipyrromethene (BODIPY) compounds have been the subject of intense scrutiny over the past few decades owing to their unique properties and various applications; however, structurally characterized BODIPY-centered radicals are still limited and isolable radicals derived from heavier analogues of BODIPY have never been described. Herein, we report the facile isolation and structural characterization of the first series of radicals [K(THF)(2)][(DPMBF2)-D-Trip] (4), [K(?(6)-toluene)][(DPMAlI2)-D-Trip] (5), and [(DPMGaI)-D-Trip((PrNHC)-Pr-i)] (6) derived from boron-dipyrromethene (DPMBF2)-D-Trip (1) and its heavier analogues (DPMAlI2)-D-Trip (2) and (DPMGaI2)-D-Trip (3). Spectroscopy analysis, X-ray crystallography, and theoretical calculations reveal that one-electron reduction results in increasing delocalization over the dipyrromethene scaffold and the unpaired electrons in 4-6 are mainly delocalized over the dipyrromethene backbone with almost negligible spin density on the group 13 element centers.
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