4.6 Review

Rational design of stable functional metal-organic frameworks

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Reticular Design of Precise Linker Installation into a Zirconium Metal-Organic Framework to Reinforce Hydrolytic Stability

Yongwei Chen et al.

Summary: In this study, a Zr-based MOF, NU-600, was used to demonstrate the construction of multi-component MOFs with unprecedented complexity and control by inserting two linear linkers with different lengths into distinct pockets. It was found that increasing the connectivity of Zr6 nodes remarkably reinforced the hydrolytic stability of these linker-inserted MOFs while maintaining their water uptake capacity and pore-filling pressure. Additionally, introducing hydrophilic -OH groups into the linkers effectively shifted the pore-filling step to lower partial pressures. This methodology provides a powerful strategy to enhance the structural stability of other MOF frameworks and promotes advancements in fundamental sciences and practical applications.

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Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal-Organic Framework to Boost Xe/Kr Separation

Wei Gong et al.

Summary: Efficient separation of Xe/Kr mixtures is achieved using a Zr-MOF material called NU-1107, which can be engineered to have selective separation capabilities. The best performing material, NU-1107-Ag(I), demonstrates a high selectivity of 13.4 for a 20:80 v/v Xe/Kr mixture, surpassing other reported MOF materials. DFT calculations confirm the strong interaction between Xe and Ag(I) sites in NU-1107-Ag(I).

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Zhijie Chen et al.

Summary: This article summarizes recent progress in the synthesis and application of highly porous metal-organic frameworks (MOFs) inspired by reticular chemistry. The authors first introduce the synthesis of NU-1500 and NU-1501 using reticular chemistry and discuss their potential applications in storing clean energy gases such as hydrogen and methane. They then present the rational synthesis of highly porous and stable Zr-MOFs based on edge-transitive nets, and provide an overview of the potential applications of these MOFs, including water capture, catalysis, gas storage, etc. Overall, this Account provides valuable insights and inspiration for the development of next-generation highly porous materials for energy and environment-related applications.

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Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal-Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold

Wei Gong et al.

Summary: The sorption of water vapor by metal-organic frameworks (MOFs) has attracted significant attention due to its potential applications in various areas. In this study, a series of robust Zr-MOFs based on a unique [2.2]paracyclophane (PCP) scaffold were designed using reticular chemistry. The water vapor sorption performances of these Zr-MOFs were found to be highly dependent on their framework topology and pore metric, with two Zr-MOFs exhibiting high uptake capacities and excellent working capacity.

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Zhijie Chen et al.

Summary: This review summarizes the progress in the development of advanced porous materials for hydrogen storage, including MOFs, covalent organic frameworks, porous organic polymers, carbon-based materials, and zeolites. The focus is on composite materials that encapsulate light elements for hydrogen storage in porous materials, and the future prospects for porous materials as a viable technology for hydrogen storage.
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Wei Gong et al.

Summary: Metal-organic frameworks (MOFs) or porous coordination polymers (PCPs), known for their high porosity and diverse functionality, have garnered significant interest. Chiral MOFs (CMOFs) have found wide applications in chiral recognition, separation, and catalysis. This review summarizes the recent progress in CMOFs, including design strategies, synthetic approaches, and cutting-edge applications, with a focus on asymmetric catalysis, enantioselective separation, enantioselective recognition, and sensing.

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Chiral Metal-Organic Cluster Induced High Circularly Polarized Luminescence of Metal-Organic Framework Thin Film

Yi-Hong Xiao et al.

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Kecheng Wang et al.

Summary: Metal-organic frameworks (MOFs) are porous crystalline materials made up of organic ligands and metal ions/clusters. Their unique advantages have attracted increasing attention in recent years, showing great potential in various applications. In alkaline operational environments, the stability of MOFs against bases is crucial for achieving high performance and long cycling life. Therefore, the development of base-stable MOFs has become a critical research direction in this field.

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Zhijie Chen et al.

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Hao Jiang et al.

Summary: Reticular chemistry has enabled the synthesis of diverse metalorganic frameworks and covalent organic frameworks through the linking of well-defined molecular building blocks into crystalline extended frameworks. The methodologies in this field are based on building blocks, targeted nets, and isoreticular chemistry, with emphasis on edge-transitive nets for the design of MOFs. Emerging concepts such as merged-net approach and net-coded building units show potential in synthesizing intricate or multi-component MOFs. Challenges and opportunities exist in the modification, expansion, and contraction of building blocks for the assembly of increasingly intricate frameworks.

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