4.7 Article

Why a simple vanadate is inefficient as a catalyst in the oxidation of alkanes with H2O2 - the long-standing puzzle is solved

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Summary: Organohalides are important and useful compounds in organic chemistry, but their traditional halogenation methods generate environmentally unfriendly by-products. Biomimetic halogenation inspired by nature offers a green alternative. This review summarizes the recent progress of biomimetic halogenation using vanadium-dependent haloperoxidase, discussing its challenges, opportunities, and synthetic applications.

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