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Boundary research between organic conductors and transistors: new trends for functional molecular crystals

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CRYSTENGCOMM
卷 25, 期 27, 页码 3846-3860

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ce00305a

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In organic transistors, the contact resistance between the organic semiconductor and electrode is a challenge. By using a buffer layer and high-conductivity organic conductors as electrodes, the depletion layer at the semiconductor surface can be reduced. A self-contact transistor, based on chemically doping organic semiconductors, has been proposed to fabricate specific organic conductor electrodes for each semiconductor, resulting in low contact resistance. Organic conductors based on organic semiconductors are crucial for further development and fabrication of these devices.
In organic transistors, the contact resistance at the interface between the organic semiconductor (OSC) and electrode reduces the device performance. To solve this problem, a buffer layer is inserted between the electrode and OSC layer to decrease the depletion layer that forms at the OSC surface. Especially in bottom-contact transistors, the effects of interfacial potentials and carrier traps can be suppressed using high-conductivity organic-conductors and carbon pastes as electrodes. Accordingly, a self-contact transistor was proposed based on chemically doping OSCs. This technique enables us to fabricate organic conductor electrodes specific to each OSC, resulting in transistors with low contact resistance. However, organic conductors based on OSCs are essential to expand the fabrication of these devices using the doping method. Consequently, OSCs have been used to develop a promising new class of organic conductors with high conductivity and excellent thermoelectric properties. Although developing organic conductors based on OSCs remains relatively unexplored, it is expected to become a new trend in functional molecular compounds.

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