☆ 4.7 Article

Comparison of group 4 and thorium M(IV) substituted cyclopentadienyl silanide complexes

DALTON TRANSACTIONS (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Inorganic & Nuclear

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes

Stephen T. . Liddle et al.

Summary: The salt metathesis reactions of the yttrium methane-diide iodide complex [Y(BIPM)(I)(THF)2] with the group 1 silanide ligand-transfer reagents MSiR3 (M = Na, R3 = tBu2Me or tBu3; M = K, R3 = (SiMe3)3) yielded the yttrium methanediide silanide complexes [Y(BIPM)(SitBu2Me)(THF)] (1), [Y(BIPM)(SitBu3)(THF)] (2), and [Y(BIPM){Si(SiMe3)3}-(THF)] (3). These complexes provide rare examples of structurally authenticated rare earth metal-silicon bonds and were characterized by various spectroscopic techniques. Density functional theory calculations revealed the predominantly ionic Y-Si bonding in 1-3. Reactivity studies showed the preferential 1,2-migratory insertion of unsaturated substrate into the Y-Si bond, as well as [2+2] cycloaddition reaction at the Y=C bond with certain substrates.

INORGANIC CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

29Si NMR Spectroscopy as a Probe of s- and f-Block Metal(II)-Silanide Bond Covalency

Benjamin L. L. Reant et al.

Summary: In this study, Si-29 NMR spectroscopy and DFT calculations were combined to investigate the covalency in the chemical bonding of s- and f-block metal-silicon bonds. The results showed a wide range of metal-bound Si-29 NMR isotropic chemical shifts and linear correlations between dSi and computed delocalization indices. The calculations revealed dominant s- and d-orbital character in the bonding of these silanide complexes.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Nuclear Science & Technology

The potentiality of thermal safety and economy of the U3Si2-SiC system in PWR

Sihong He et al.

ANNALS OF NUCLEAR ENERGY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

f-Element silicon and heavy tetrel chemistry

Benjamin L. L. Reant et al.

CHEMICAL SCIENCE (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Polarised covalent thorium(iv)- and uranium(iv)-silicon bonds

Benjamin L. L. Reant et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

One simple Ir/hydrosilane catalytic system for chemoselective isomerization of 2-substituted allylic ethers

Weiwei Gao et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Physical

High catalytic activity and selectivity in hydrosilylation of new Pt(II) metallosupramolecular complexes based on ambidentate ligands

Anna Walczak et al.

JOURNAL OF CATALYSIS (2019)

添加到收藏夹

Review Chemistry, Physical

Transition metal silicides: fundamentals, preparation and catalytic applications

Xiao Chen et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

添加到收藏夹

Article Chemistry, Organic

Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins

Venu Srinivas et al.

ORGANIC LETTERS (2018)

添加到收藏夹

Review Green & Sustainable Science & Technology

Viability of thorium-based nuclear fuel cycle for the next generation nuclear reactor: Issues and prospects

Uguru Edwin Humphrey et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

添加到收藏夹

Article Materials Science, Ceramics

Uranium nitride-silicide advanced nuclear fuel: higher efficiency and greater safety

Tashiema L. Wilson et al.

ADVANCES IN APPLIED CERAMICS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Trimethylsilylcyclopentadienyl (Cp) Uranium Chemistry: Synthetic and Structural Studies of Cp4U and Cp3UX (X = Cl, I, Me)

Cory J. Windorff et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2017)

添加到收藏夹

Review Chemistry, Physical

Effects of Rare Earth Metals on Steel Microstructures

Fei Pan et al.

MATERIALS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Cambridge Structural Database

Colin R. Groom et al.

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS (2016)

添加到收藏夹

Article Materials Science, Multidisciplinary

Thermophysical properties of U3Si2 to 1773 K

J. T. White et al.

JOURNAL OF NUCLEAR MATERIALS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthetic Aspects of (C5H4SiMe3)3Ln Rare-Earth Chemistry: Formation of (C5H4SiMe3)3Lu via [(C5H4SiMe3)2Ln]+ Metallocene Precursors

Jeffrey K. Peterson et al.

ORGANOMETALLICS (2013)

添加到收藏夹

Software Review Chemistry, Multidisciplinary

WinGX and ORTEP for Windows: an update

Louis J. Farrugia

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2012)

添加到收藏夹

Review Chemistry, Multidisciplinary

Molecular Single-Bond Covalent Radii for Elements 1-118

Pekka Pyykko et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

添加到收藏夹

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Lanthanum does form stable molecular compounds in the+2 oxidation state

Peter B. Hitchcock et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

添加到收藏夹

Article Chemistry, Physical

A comparative study of the reactivity of Zr(IV), Hf(IV) and Th(IV) metallocene complexes: Thorium is not a Group IV metal after all

Kimberly C. Jantunen et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synthetic development and chemical reactivity of transition-metal silylene complexes

Rory Waterman et al.

ACCOUNTS OF CHEMICAL RESEARCH (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synthesis and characterization of scandium silyl complexes of the type CP*2ScSiHRR′.: σ-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons

AD Sadow et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Reactions of oligosilyl potassium compounds with Group 4 metallocene dichlorides

C Kayser et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2003)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Organolutetium complexes in σ-bond metathesis reactions involving silicon.: Catalysts for the hydrogenolysis of Si-C bonds

I Castillo et al.

ORGANOMETALLICS (2001)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

New reagents to introduce weakly coordinating anions of type Al(ORF)4-:: synthesis, structure and characterization of Cs and trityl salts

I Krossing et al.

JOURNAL OF FLUORINE CHEMISTRY (2001)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chemistry with ADF

G te Velde et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2001)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.