期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 55, 页码 8576-8579出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02038j
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The research on aqueous iron-ion batteries (AIIBs) is limited by the lack of suitable cathode materials. In this study, tunnel-like VO2 is proposed as a cathode material, delivering a high capacity of 198 mA h g(-1) at 0.2 A g(-1). The AIIB shows good cycling performance, retaining 78.9% of its initial capacity after 200 cycles. The unique structure of VO2 and the multiple valence states of vanadium enable the reversible storage of Fe2+ during cycling. This work presents a new choice for the cathode and has considerable development prospects in AIIBs.
The research on aqueous iron-ion batteries (AIIBs) is still in its early stages and highly limited by the lack of suitable cathode materials. In this study, we propose using tunnel-like VO2 as a cathode material, which delivers a high capacity of 198 mA h g(-1) at 0.2 A g(-1). Besides, the AIIB exhibits appreciable cycling performance, retaining 78.9% of its initial capacity after 200 cycles. The unique structure of VO2 and the multiple valence states of vanadium in VO2 enable the reversible storage of Fe2+ during cycling. This work presents a new choice for the cathode and considerable development prospects in AIIBs.
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