Biomass-based activated carbons produced by chemical activation with H3PO4 as catalysts for the transformation of a-pinene to high-added chemicals

In the era of ecology and careful care for the environment, it becomes important to use renewable raw materials of plant origin, which are often more easily available and cheaper. One of the important and rapidly developing directions of research are works related to the use of waste plant biomass; an example of this trend is the production of activated carbons from food industry waste. One of the examples of the application of derived from biomass activated carbons can be using them as catalysts for the isomerization of terpene compounds. Carbons based on waste biomass are characterized by the minimal amount of waste formation during their manufacture, and their use in the isomerization reaction allows to obtain high conversion of organic raw material and high selectivities of transformation to the desired products, making these carbons environmentally friendly substitutes for the catalysts used usually in this process. In this work, obtained carbonaceous catalysts were tested in the process of isomerization of a-pinene to high value chemicals (mainly camphene and limonene). Under the most favorable conditions (activated carbon from sunflower husks content in reaction mixture 5 wt%, temperature 180 degrees C, and reaction time 100 min), a-pinene was completely converted (conversion 100 mol%) with high selectivity towards camphene (54 mol%). To prepare activated carbons, biomass precursors (orange peels, sunflower husks, spent coffee grounds) were activated with 85% H3PO4 through the chemical activation. The obtained materials were characterized by such methods as sorption N2 at - 196 degrees C, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), and X-ray fluorescence (XRF) to determine the relationship between their textural-chemical properties and catalysts activity in isomerization process. The synthesized materials were characterized by a specific surface area in the range of 930-1764 m2, total pore volume in the range of 0.551-1.02 cm3/g, and total acid-site concentrations in the range of 1.47-2.33 mmol/g. These results showed that textural parameters of the obtained activated carbons have the important role in the isomerization of a-pinene.

Automated summary

In the era of ecology and careful care for the environment, it is important to use renewable raw materials of plant origin. Research on the use of waste plant biomass, such as producing activated carbons from food industry waste, is a rapidly developing direction. Carbons based on waste biomass offer environmentally friendly substitutes for catalysts in isomerization reactions, allowing for high conversion of organic raw materials and desired product selectivities.