4.7 Article

Recent trends in phenol synthesis by photocatalytic oxidation of benzene

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

Photocatalytic property of WO3 modified with noble metal co-catalysts towards selective hydroxylation of benzene to phenol under visible light irradiation

Shinya Higashimoto et al.

Summary: Phenol was synthesized directly from benzene under visible-light irradiation in the presence of water and oxygen. The effects of several noble metal co-catalysts on the selective hydroxylation of benzene over WO3 photocatalysts were extensively investigated. The photocatalytic activities of WO3 for phenol formation strongly depended on the co-catalyst, with the following order: Pt-WO3 > Au-WO3 > Pd-WO3. Furthermore, bimetal co-catalysts, such as Pd/Pt, Pd/Au, and Pt/Au, deposited on WO3 photocatalyst were also studied. The Pd/Pt-WO3 photocatalyst exhibited the highest photocatalytic activity for phenol formation due to an effective oxygen reduction reaction (ORR) facilitated by the bimetallic Pd/Pt co-catalyst.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Article Chemistry, Physical

A novel Cr-doped CdS/ZnO nanocomposite for efficient photocatalytic hydroxylation of benzene to phenol

Weiwei Han et al.

Summary: Cr-doped CdS/ZnO (Cr-CdS/ZnO) nanocomposites were synthesized and characterized using different physicochemical methods. The photocatalytic activity of the nanocomposites for benzene hydroxylation was evaluated, and the impacts of reaction conditions were investigated. The enhanced visible-light absorption and photocatalytic performance of the synthesized composites enable the potential of Cr-CdS/ZnO nanocomposites for the application of photocatalytic green synthesis.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

Article Engineering, Environmental

Evolution of intrinsic 1-3D WO3 nanostructures: Tailoring their phase structure and morphology for robust hydrogen evolution reaction

R. Rajalakshmi et al.

Summary: This study successfully synthesized various morphologies of WO3 nanostructures by tuning hydrothermal synthesis parameters and surfactants, with 1D nanorods showing superior electrocatalytic performance for hydrogen evolution reaction under extreme pH conditions.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

One-step oxidation of benzene to phenol with H3PW12O40 under photoirradiation: Effect of operating conditions

Ziru Wang et al.

Summary: In this study, a heteropolyacid H3PW12O40 was used as a photocatalyst for the one-pot oxidation of benzene with O-2 to synthesize phenol with high yield and selectivity. The addition of acetonitrile to the reaction solution inhibited the overoxidation of phenol, allowing for efficient phenol formation. Moreover, the H3PW12O40 photocatalyst showed stability and could be reused with minimal decrease in phenol formation rate.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Characterization of Surface Species during Benzene Hydroxylation over a NiO-Ceria-Zirconia Catalyst

Jennifer N. Jocz et al.

Summary: NiO/ceria-zirconia (CZ) is a promising catalyst for the selective oxidation of benzene, with Lewis-acidic NiO clusters activating C-H bonds and the redox-active CZ support supplying active oxygen species for the reaction. In this study, surface species formed from benzene, water, oxygen, phenol, and catechol on a NiO/CZ catalyst were examined using transmission in situ infrared (IR) spectroscopy. The presence of NiO clusters and the CZ support played crucial roles in benzene activation, leading to the formation of different surface species and indicating the potential of NiO/CZ for catalyzing the direct conversion of benzene to phenol with the addition of water enhancing the reaction process.

LANGMUIR (2022)

Article Engineering, Environmental

Highly efficient photocatalytic H2O2 production with cyano and SnO2 co-modified g-C3N4

Chengcheng Chu et al.

Summary: In this study, the photocatalytic properties of g-C3N4 for H2O2 production were enhanced by co-modification with cyano group and SnO2 nanocrystal. The modified g-C3N4 showed excellent performance with a H2O2 yield rate of 703.4 mu M g(-1)h(-1) under visible light illumination, indicating a promising approach to improve the photocatalytic activity of g-C3N4.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Carbon encapsulated bimetallic FeCo nanoalloys for one-step hydroxylation of benzene to phenol

Lingdong Zeng et al.

Summary: Carbon encapsulated iron catalysts with alloyed Fe and Co cores demonstrate improved catalytic activity for hydroxylation of benzene to phenol by activating H(2)O(2). The phenol yield and selectivity of FeCo@C catalyst are significantly higher than those of Fe@C and Co@C catalysts. This alloyed catalyst shows promise for liquid-phase reactions using H(2)O(2) as the oxidant.

APPLIED CATALYSIS A-GENERAL (2022)

Article Chemistry, Physical

Unique functionalities of carbon shells coating on ZnFe2O4 for enhanced photocatalytic hydroxylation of benzene to phenol

Baoying Yang et al.

Summary: The encapsulation of ZFO with carbons enhances its photocatalytic activity and durability by protecting ZFO from corrosion and metal leaching, facilitating charge separation, and increasing benzene adsorption. The resulting ZFO@C photocatalyst is expected to have broad applications in green synthesis of fine chemicals.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Multidisciplinary

Fully conversing and highly selective oxidation of benzene to phenol based on MOF-derived CuO@CN photocatalyst

Longjiang Sun et al.

CHINESE CHEMICAL LETTERS (2022)

Review Engineering, Environmental

Properties, optimized morphologies, and advanced strategies for photocatalytic applications of WO3 based photocatalysts

Pooja Shandilya et al.

Summary: The development of WO3 based photocatalysts for environmental remediation and energy production has attracted global attention due to its visible light absorption, excellent electronic and morphological properties, high stability, and enhanced photoactivity. With its non-toxicity, biocompatibility, low cost, and tunable band gap, WO3 shows promise for various applications. The review covers different properties, fabrication methods, strategies for enhancing photocatalytic performance, typical applications, and future prospects of WO3 based nanocomposites.

JOURNAL OF HAZARDOUS MATERIALS (2022)

Article Chemistry, Physical

Constructing the separation pathway for photo-generated carriers by diatomic sites decorated on MIL-53-NH2(Al) for enhanced photocatalytic performance

Gang Wang et al.

Summary: This paper reports a new strategy to enhance the high yield production of phenol by using diatomic synergistic modulation. The strategy effectively controls the separation of photo-generated carriers on a designed photocatalyst, leading to a significant enhancement of benzene photo-oxidation to phenol.

NANO RESEARCH (2022)

Article Chemistry, Physical

Enhanced Photocatalytic Benzene Oxidation to Phenol over Monoclinic WO3 Nanorods under Visible Light

Ziru Wang et al.

Summary: In this study, Pt-loaded 1D monoclinic WO3 nanorods (Pt/m-WNR) showed higher activity in the photocatalytic oxidation of benzene to phenol under ambient conditions and visible light than other Pt/WO3 catalysts with different crystal structures and morphologies. Pt/m-WNR exhibited high stability in repeated reactions. The specific performance of Pt/m-WNR was attributed to the efficient reduction of O-2 to produce hydroxyl radicals via H2O2 as an intermediate, as evidenced by both experimental and theoretical findings.

ACS CATALYSIS (2022)

Review Biochemistry & Molecular Biology

Recent Advances in the Heterogeneous Photocatalytic Hydroxylation of Benzene to Phenol

Weiwei Han et al.

Summary: This paper presents a comprehensive review of recent advancements in the photocatalytic hydroxylation of benzene to phenol, including various heterogeneous photocatalysts and their modification methods. The challenges and promising directions for enhancing the catalytic performances are also discussed.

MOLECULES (2022)

Article Chemistry, Multidisciplinary

An efficient photocatalyst based on H5PMo10V2O40/UiO-66-NH2 for direct hydroxylation of benzene to phenol by H2O2

Xu Jia et al.

Summary: An efficient photoactive catalyst system was prepared by the recombination of H5PMo10V2O40 and UiO-66-NH2, which could effectively catalyze the direct hydroxylation of benzene to phenol. Under the optimum condition, the yield and selectivity were 14.08% and 98.8% respectively. The catalyst maintained good performance after 5 catalytic cycles.

RSC ADVANCES (2022)

Article Chemistry, Multidisciplinary

Light-Induced Efficient Hydroxylation of Benzene to Phenol by Quinolinium and Polyoxovanadate-Based Supramolecular Catalysts

Yaqi Gu et al.

Summary: A series of supramolecular catalysts based on alkoxohexavanadate anions and quinolinium ions were demonstrated for the photocatalytic hydroxylation of benzene to phenol with competitive good yield, high selectivity and high atom availability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Selective modification of ultra-thin g-C3N4 nanosheets on the (110) facet of Au/BiVO4 for boosting photocatalytic H2O2 production

Haiyang Shi et al.

Summary: In this study, a BiVO4 single crystal with selective comodification of ultra-thin g-C3N4 and Au was prepared for the first time to improve H2O2 production efficiency, achieving excellent performance in H2O2 production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Engineering, Chemical

Oxo-vanadium (IV) phthalocyanine implanted onto the modified SBA-15 as a catalyst for direct hydroxylation of benzene to phenol in acetonitrile-water medium: A kinetic study

Shohreh Farahmand et al.

Summary: This study achieved highly selective direct hydroxylation of benzene using a vanadyl phthalocyanine catalyst and found that the mixed solvent CH3CN-H2O played a key role in the reaction progress.

CHEMICAL ENGINEERING SCIENCE (2021)

Article Chemistry, Physical

A homogeneous Cu-based polyoxometalate coupled with mesoporous TiO2 for efficient photocatalytic H2 production

Kangwei Ma et al.

Summary: In this study, a noble-metal-free polyoxometalate Cu3POM was successfully coupled with mesoporous, multiphase TiO2 to create a highly efficient photocatalytic system for hydrogen production. The composite system exhibited excellent photocatalytic activity by increasing active sites, enhancing stability, and narrowing band gap. This innovative combination provides new insights into the design of efficient photocatalytic materials for H₂ production.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Review Chemistry, Physical

Review of some transition metal-based mesoporous catalysts for the direct hydroxylation of benzene to phenol (DHBP)

Nafiseh Rahmani et al.

Summary: Mesoporous transition metal-based catalysts act as efficient catalytic supports and catalysts, providing high selectivity and controllability in the catalysis process. This emerging area offers researchers the opportunity to introduce novel heterogeneous catalysts.

MOLECULAR CATALYSIS (2021)

Article Engineering, Environmental

Visible-light photooxidation of benzene to phenol in continuous-flow microreactors

Xiaoqi Shi et al.

Summary: In this study, phenol was successfully synthesized through photooxidation, reaching a high yield of 94% and selectivity over 99% under optimized conditions. The photomicroreactor with blue LEDs as an eco-friendly light source demonstrated significant advantages, while a reaction kinetic model was established to further understand the photooxidation mechanism.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Engineering, Chemical

Enhanced Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over g-C3N4 Quantum Dots-Modified Fe-SBA-15 Catalysts: Synergistic Effect Among Fe Species, g-C3N4 QDs, and Porous Structure

Lizhen Qin et al.

Summary: g-C3N4 quantum dots (QDs) have shown great potential in catalytic applications, with the decoration of Fe-SBA-15 channels enhancing the hydroxylation of benzene to phenol. Through in-depth analysis and characterization, it was found that the synergy between g-C3N4 QDs and Fe-SBA-15 plays a crucial role in the catalytic system, leading to a maximum phenol yield of 41.2%.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Engineering, Chemical

Synergistic Effect between Fe and Cu Species on Mesoporous Silica for Hydroxylation of Benzene to Phenol

Yuzhou Wu et al.

Summary: In this study, Cu/Fe-SBA-15 catalyst was synthesized and used for the direct hydroxylation of benzene, demonstrating good catalytic activity. The interaction and synergistic effect between iron and copper sites were also investigated.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

Article Chemistry, Physical

Efficient photocatalytic conversion of benzene to phenol on stabilized subnanometer WO3 quantum dots

Akihide Ohno et al.

Summary: Band engineering using quantum size effect is utilized to enhance the photocatalytic activity of subnanometer WO3 quantum dots, leading to efficient conversion of organic compounds such as benzene to phenol without decomposition into CO2 under ultraviolet illumination.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

A novel heterogeneous catalyst NH2-MIL-88/PMo10V2 for the photocatalytic activity enhancement of benzene hydroxylation

PanPan Xu et al.

Summary: This study presents a highly selective photocatalytic reaction for hydroxylation of benzene to phenol using NH2-MIL-88/PMo10V2-3 catalyst and H2O2 oxidant, with a yield of 24% and a selectivity of 99% under optimal reaction conditions. The immobilization of heteropoly acid (PMo10V2) in metal-organic frameworks (NH2-MIL-88) plays a key role in anchoring NH3+ cations to form stable heterogeneous photocatalysts, providing potential applications in green and highly efficient photocatalytic synthesis of other organic compounds and environmental applications.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Photocatalytic hydroxylation of benzene to phenol over organosilane-functionalized FeVO4 nanorods

Danlei Wei et al.

Summary: The study demonstrates that silylated iron vanadate nanorods can serve as promising photocatalysts for directing hydroxylation of benzene to phenol, by utilizing the unique benefits of covalently bonded organosilane groups to achieve kinetic control of heterogeneous photocatalytic reactions.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Multidisciplinary

Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives

Alexey S. Cherevan et al.

ADVANCED SCIENCE (2020)

Article Chemistry, Physical

One-step photocatalytic benzene hydroxylation over iron (II) phthalocyanine: A new application for an old catalyst

Saeid Asghari et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Polyoxometalate-Based Compounds for Photo- and Electrocatalytic Applications

Ning Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

Z-scheme photocatalytic production of hydrogen peroxide over Bi4O5Br2/g-C3N4 heterostructure under visible light

Xuesong Zhao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Review Chemistry, Multidisciplinary

Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

Alexander Anyushin et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Engineering, Chemical

Selective photocatalytic oxidation of benzene to phenol using carbon nanotube (CNT)-supported Cu and TiO2 heterogeneous catalysts

Venkata D. B. C. Dasireddy et al.

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS (2018)

Article Chemistry, Physical

Selective photocatalytic benzene hydroxylation to phenol using surface- modified Cu2O supported on graphene

Jinbao He et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

Photosensitization and Photocatalysis-Perspectives in Organic Synthesis

Clement Michelin et al.

ACS CATALYSIS (2018)

Review Chemistry, Multidisciplinary

Dioxygen in Polyoxometalate Mediated Reactions

Ira A. Weinstock et al.

CHEMICAL REVIEWS (2018)

Article Chemistry, Physical

Stable Fe/ZSM-5 Nanosheet Zeolite Catalysts for the Oxidation of Benzene to Phenol

Lingqian Meng et al.

ACS CATALYSIS (2017)

Article Chemistry, Multidisciplinary

Hydroxylation of Benzene via C-H Activation Using Bimetallic CuAg@g-C3N4

Sanny Verma et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

Review Chemistry, Inorganic & Nuclear

Hybrid polyoxometalate materials for photo(electro-) chemical applications

James J. Walsh et al.

COORDINATION CHEMISTRY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C -H Amination and Hydroxylation

Yi-Wen Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Chemistry, Multidisciplinary

Recent Advances in Polyoxometalate-Catalyzed Reactions

Sa-Sa Wang et al.

CHEMICAL REVIEWS (2015)

Review Chemistry, Organic

One-Step Selective Hydroxylation of Benzene to Phenol

Shunichi Fukuzumi et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Physical

Selective oxidation of benzene to phenol by Fe-CN/TS-1 catalysts under visible light irradiation

Xiangju Ye et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2014)

Article Chemistry, Physical

Ambient Oxidation of Benzene to Phenol by Photocatalysis on Au/Ti0.98V0.02O2: Role of Holes

Perumal Devaraji et al.

ACS CATALYSIS (2014)

Article Chemistry, Multidisciplinary

Highly Selective Hydroxylation of Benzene to Phenol by Wild-type Cytochrome P450BM3 Assisted by Decoy Molecules

Osami Shoji et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-dicyano-p-benzoquinone

Kei Ohkubo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Layered Silicate as an Excellent Partner of a TiO2 Photocatalyst for Efficient and Selective Green Fine-Chemical Synthesis

Yusuke Ide et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Selective oxidation of benzene to phenol by FeCl3/mpg-C3N4 hybrids

Pengfei Zhang et al.

RSC ADVANCES (2013)

Article Chemistry, Multidisciplinary

Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts

Kei Ohkubo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Physical

Hierarchical mesoporous Fe/ZSM-5 with tunable porosity for selective hydroxylation of benzene to phenol

Bharat S. Rana et al.

JOURNAL OF MATERIALS CHEMISTRY (2010)

Article Chemistry, Physical

A Density Functional Theory Study of Direct Oxidation of Benzene to Phenol by N2O on a [FeO]1+-ZSM-5 Cluster

Mehmet Ferdi Fellah et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

Article Chemistry, Multidisciplinary

Determination of Oxygen Sources for Oxidation of Benzene on TiO2 Photocatalysts in Aqueous Solutions Containing Molecular Oxygen

Thuan Duc Bui et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Multidisciplinary

Efficient Visible-Light-Induced Photocatalytic Activity on Gold-Nanoparticle-Supported Layered Titanate

Yusuke Ide et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Applied

Direct benzene conversion to phenol in a hybrid photocatalytic membrane reactor

Raffaele Molinari et al.

CATALYSIS TODAY (2009)

Article Chemistry, Multidisciplinary

Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light

Xiufang Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Photocatalytic hydroxylation of aromatic ring by using water as an oxidant

Hisao Yoshida et al.

CHEMICAL COMMUNICATIONS (2008)

Article Chemistry, Multidisciplinary

Adsorption-driven photocatalytic activity of mesoporous titanium dioxide

Y Shiraishi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)