State-of-the-art and perspectives in transition metal-based heterogeneous catalysis for selective hydrogenation of cinnamaldehyde

Chemoselective liquid phase hydrogenation of cinnamaldehyde (CAL) by employing transition-metal-based heterogeneous catalysts has been investigated by a lot of researchers worldwide with a view to obtain the desired products such as cinnamyl alcohol or hydrocinnamaldehyde. Both the products have significant wideranging applications in pharmaceuticals, perfumery, cosmetics and chemical industries. The present review therefore summarizes development in the last five years towards selective CAL hydrogenation over transition metal-based catalysts. The review is categorized into two major sections; selective hydrogenation of CAL to cinnamyl alcohol (COL) and selective hydrogenation of CAL to hydrocinnamaldehyde (HCAL) over various noble metals (Pt, Pd, Ru, Au, Ir and Ag) and non-noble metal-based catalysts (Ni, Co and Cu). A number of tailored metal-based catalytic systems for selective CAL hydrogenation reported in current years have been systematically reviewed based on the above categories. In addition, effect of reaction variables such as catalyst preparation, nature of solvents, reaction conditions has been deliberated. The review has been concluded with discussion on limitations encountered for noble metal as well as non-noble metal-based catalysts for selective CAL hydrogenation along with the future scope. Overall, the present review focuses on the fundamental principles of the transition metal-based catalysts reported for selective CAL hydrogenation.

Automated summary

This review summarizes the recent developments in chemoselective liquid phase hydrogenation of cinnamaldehyde using transition metal-based catalysts, focusing on the selective hydrogenation to cinnamyl alcohol and hydrocinnamaldehyde. The review discusses the use of noble metals (Pt, Pd, Ru, Au, Ir, and Ag) and non-noble metals (Ni, Co, and Cu) as catalysts, and considers the effect of reaction variables. The limitations and future prospects of both noble metal and non-noble metal catalysts for selective hydrogenation of cinnamaldehyde are also discussed.