期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 58, 页码 9001-9004出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02644b
关键词
-
This study describes the first example of a binary cocrystal comprised of SnPh3Cl and PPh3, in which the components are organized via short and directional tetrel bonds (TtB) between tin and phosphorus. DFT elucidates, for the first time, the factors influencing the strength of TtBs involving heavy pnictogens. A CSD survey reveals that such TtBs are also present and determinative in single component molecular systems, highlighting their significant potential as tuneable structure-directing elements.
The first example of a binary cocrystal, comprised of SnPh3Cl and PPh3, whose components are organized via short and directional tetrel bonds (TtB) between tin and phosphorus, is described. DFT elucidates, for the first time, the factors influencing the strength of TtBs involving heavy pnictogens. A CSD survey reveals that such TtBs are also present and determinative in single component molecular systems, highlighting their significant potential as tuneable structure-directing elements.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据