期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 11, 期 29, 页码 15792-15801出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ta02128a
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We report novel composite sodium silicate electrolytes with high ionic conductivity for solid-state sodium-ion batteries (SIBs). These electrolytes offer a viable alternative to lithium-ion batteries (LIBs) with their low cost, abundance of sodium, and high safety.
Solid-state sodium-ion batteries (SIBs) are a viable alternative to existing lithium-ion batteries (LIBs) due to the low cost and abundance of sodium and the high safety of using solid-state components. Here, we report novel composite sodium silicate electrolytes exhibiting high ionic conductivity for solid-state SIBs. Rare-earth silicates (3 + x)Na2O-Gd2O3-6SiO(2) (NGS, x = 0, 0.05, 0.1, 0.15, 0.2, and 0.25 mol%, following the composition Na3GdSi3O9), are prepared by the conventional solid-state method. The phase and morphology of the prepared ceramic electrolytes are characterized using powder X-ray diffraction and scanning electron microscopy. The electrical properties of the samples are investigated using impedance spectroscopy, with NGS 0.15 mol% Na2O, (3.45 Na2O-Gd2O3-6 SiO2; NGS15) sintered at 1075 & DEG;C for 6 h exhibiting the highest ionic conductivity of 7.25 x 10(-4) S cm(-1) at 25 & DEG;C comparable to that of NASICON electrolytes. Na plating/stripping is conducted to demonstrate the compatibility of the prepared ceramic electrolyte with a sodium metal anode that exhibits exceptional stability for 1000 h at a current density of 0.1 mA cm(-2). A hybrid battery built using a Na anode, an NGS15 ceramic electrolyte with 20 & mu;L of liquid electrolyte on the cathode side, and a Na3V2(PO4)(3) cathode exhibited an initial discharge capacity of 90 mA h g(-1) at 0.1C with a capacity retention of 98.01% for 100 charge-discharge cycles, highlighting the potential of the sodium rare-earth silicate as a sodium battery separator and electrolyte.
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