Hybrid leaching of tantalum and other valuable metals from tantalum capacitor waste

We propose a novel integrated model for the recovery of tantalum from tantalum-rich waste using a combination of hydro-metallurgical and bio-metallurgical processes. To this end, leaching experiments with heterotrophs (Pseudomonas putida, Bacillus subtilis and Penicillium simplicissimum) were carried out. The heterotrophic fungal strain leached manganese with an efficiency of 98%; however, no tantalum was detected in the leachate. An unidentified species did mobilise 16% tantalum in 28 days in an experiment with non-sterile tantalum capacitor scrap. Attempts to cultivate isolate and identify these species failed. The results of a range of leaching trials resulted in an effective strategy for Ta recovery. A bulk sample of homogenised Ta capacitor scrap was first subjected to microbial leaching using Penicillium simplicissimum, which solubilised manganese and base metals. The residue was subjected to the second leach using 4 M HNO3. This effectively solubilised silver and other impurities. The residue collected after the second leach was pure tantalum in concentrated form. The hybrid model produced derives from observations from previous independent studies and shows that we can effectively recover tantalum along with silver and manganese in an efficient and environmentally friendly manner from tantalum capacitor scrap.

Automated summary

We propose a novel integrated model for recovering tantalum from tantalum-rich waste by combining hydro-metallurgical and bio-metallurgical processes. Leaching experiments with heterotrophs showed high efficiency in leaching manganese, but no tantalum was detected. An unidentified species was able to mobilize 16% tantalum in non-sterile tantalum capacitor scrap, but efforts to identify it failed. The proposed model involves microbial leaching with Penicillium simplicissimum to solubilize manganese, followed by a second leach with 4 M HNO3 to dissolve silver and impurities, resulting in concentrated pure tantalum.