期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 60, 页码 9259-9262出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02422a
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This study describes a novel ferrocene-catalyzed cyanoalkyl-imidation of aryl alkenes using cycloketone oxime esters in MeCN under redox-neutral conditions. The cycloketone oxime ester acts as a bifunctional reagent, allowing for easy access to diverse distal imido-nitriles with 100% atomic utilization. Preliminary mechanistic studies suggest that the ferrocene-ferrocenium catalytic cycle is responsible for the deconstructive functionalization of cycloketone oxime esters.
A novel ferrocene-catalyzed cyanoalkyl-imidation of aryl alkenes utilizing cycloketone oxime esters in MeCN under redox-neutral conditions is described. In this three-component reaction, the cycloketone oxime ester is employed as a bifunctional reagent, enabling easy access to diverse distal imido-nitriles with 100% atomic utilization. Preliminary mechanistic studies suggest that the ferrocene-ferrocenium catalytic cycle is responsible for the deconstructive functionalization of cycloketone oxime esters.
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