4.7 Article

Itinerant ferromagnet Re4-xMnxGe7-δ (x=0.9-1.5, δ=0.42-0.44) with incommensurate chimney-ladder structure stabilised at ambient pressure

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DALTON TRANSACTIONS
卷 52, 期 31, 页码 10657-10661

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3dt01919e

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Re4-xMnxGe7-δ (x = 0.9-1.5, δ = 0.42-0.44) is a new member of the Nowotny chimney-ladder family of compounds with an incommensurate composite structure of transition element T (Re and Mn) and Ge substructures. Theoretical calculations indicate metallic conductivity and ferromagnetic ordering, which has been experimentally observed below 157 K.
Re4-xMnxGe7-& delta; (x = 0.9-1.5, & delta; = 0.42-0.44) is a new member of the Nowotny chimney-ladder family of compounds and features an incommensurate composite structure of transition element T (Re and Mn) and Ge substructures. Our theoretical calculations indicate metallic conductivity and ferromagnetic ordering, the latter being experimentally observed below 157 K.

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