期刊
ACS MACRO LETTERS
卷 5, 期 10, 页码 1157-1161出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.6b00541
关键词
-
资金
- Japan Society for the Promotion of Science [23685023, 16H06863]
- Program for Leading Graduate Schools Integrative Graduate Education and Research Program in Green Natural Sciences
- Grants-in-Aid for Scientific Research [23685023, 26248032, 16H06863] Funding Source: KAKEN
A combination of hydrogen chloride adduct of isobutyl vinyl ether (IBVE-HCl) and various metal salts (AgOTf, AgPF6, AgSbF6, NaBArF (BArF: [3,5-(CF3)2Ph]4B)) efficiently generated initiating cationic species with different low, weakly, or non-nucleophilic counteranions (OTf-, PF6- , SbF6- , BArF-) and induced a cationic reversible-addition-fragmentation chain-transfer (RAFT) or degenerative chain-transfer (DT) polymerization of IBVE, ethyl vinyl ether, p-methoxystyrene, and a-methylstyrene (aMS) in the presence of appropriate thiocarbonylthio compounds or thioethers as reversible chain-transfer agents. The polymerization behaviors in terms of polymerization rate, polymer molecular weight, terminal structure, and stereochemistry were affected by the counteranions, whereas the molecular weight control was achieved by appropriate RAFT or DT agents for all of these counteranions. With a weakly or noncoordinating BArF anion and a trithiocarbonate, a nearly atactic poly(IBVE) with a narrow molecular weight distribution (Mw/Mn < 1.1) was obtained. When using nonoxoanions, such as SbF6- , PF6-, and BArF-, in the presence of thioethers, controlled cationic polymerization of aMS was achieved while frequent irreversible beta-proton elimination occurred using TfO-. Thus, this method widens the scope of living or controlled cationic polymerizations with various counteranions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据