期刊
ACS MACRO LETTERS
卷 5, 期 6, 页码 724-729出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.6b00279
关键词
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资金
- NSF under CCI Center for Selective C-H Functionalization [CHE-1205646]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1205646] Funding Source: National Science Foundation
C-H activation reactions have allowed us to react traditionally chemically inert bonds in molecules to develop new methods for cross-coupling reactions. This type of reactivity can be applied to conjugated polymer materials in an effort to improve existing synthetic difficulties including harsh reaction conditions, multiple monomer functionalization steps, and organometallic reagent waste. In this Viewpoint, we highlight some of the encouraging advances in direct arylation polymerization (DArP) as well as ongoing challenges for future improvement and utility.
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