期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 67, 页码 10129-10132出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02711b
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An efficient method for synthesizing highly fluorescent trisubstituted thiophenes was developed using iodine-catalyzed, base-promoted annulation and elemental sulfur as a sulfur source. These compounds show excellent photophysical properties such as solid-state fluorescence, high quantum yield, and solvatochromism. The gram-scale synthesis of the desired heterocycles was also demonstrated, making them suitable for potential applications in optoelectronic devices.
An efficient synthesis of highly fluorescent trisubstituted thiophenes was achieved via iodine-catalyzed, base-promoted annulation employing elemental sulfur as a sulfur source. The compounds exhibit excellent photophysical properties like solid-state fluorescence, high quantum yield and solvatochromism. As these thiophene derivatives have potential application in the development of optoelectronic devices, gram-scale synthesis of the desired heterocycles was demonstrated.
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