A biphenyl-spaced bis-pyrazolylpyridine ligand forms a dimetallic helical coordination cage when interacting with ferrous ions, which encapsulates an Fe3+ tris-anilate complex. The host-guest interaction breaks the symmetry of the Fe2+ centers, resulting in a differential spin crossover behavior that can be studied in detail using crystallographic methods.
A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host-guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.
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