4.6 Review

Research progress on MOFs and their derivatives as promising and efficient electrode materials for electrocatalytic hydrogen production from water

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Article Chemistry, Physical

The influence of MOF modification on oxygen evolution and reduction reaction of Fe-doped GdBaCo2O5+δ perovskite

Yu Shuai et al.

Summary: In this study, Fe doping in the B-site of GdBaCo2O5+delta (GBCO) was adopted to prepare efficient electrocatalysts for alkaline conditions. Fe doping significantly improved the oxygen evolution reaction (OER) activity of GBCO, with GdBaCo1.6Fe0.4O5+delta showing the lowest overpotential of 298 mV at 10 mA cm-2. Furthermore, the surface of GdBaCo1.6Fe0.4O5+delta was modified with MOF ZIF-67, greatly enhancing its oxygen reduction reaction (ORR) activity compared to the pristine perovskite and Pt/C.

CATALYSIS COMMUNICATIONS (2023)

Article Chemistry, Multidisciplinary

In Situ Growth of Three-Dimensional MXene/Metal-Organic Framework Composites for High-Performance Supercapacitors

Chunli Liu et al.

Summary: In this study, a versatile method for synthesizing uniform three-dimensional (3D) metal carbides, nitrides, and carbonitrides (MXenes)/metal-organic frameworks (MOFs) composites was proposed and successfully applied to create 3D hollow composites with excellent properties. This research is significant for the design and synthesis of MXene/MOF composites as well as complex hollow structures with tailorable structures and compositions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

Electron Redistributed S-Doped Nickel Iron Phosphides Derived from One-Step Phosphatization of MOFs for Significantly Boosting Electrochemical Water Splitting

Songsong Li et al.

Summary: This study reports the synthesis of high efficiency electrocatalysts based on S-doped NiFeP and improves the reaction performance by tuning the electronic structure. The research provides a new strategy for designing highly active non-noble metal catalysts.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Synthesis of Co4S3/Co9S8 nanosheets and comparison study toward the OER properties induced by different metal ion doping

Fenghua Chen et al.

Summary: Regulating the chemical composition and nanostructure and introducing dopants into two-dimensional nanomaterials is an effective strategy for designing efficient electrocatalysts. In this study, Co4S3/Co9S8 nanosheets with an ultrathin layer structure were synthesized via a solvothermal process and ultrasonic exfoliation. Different dopants (M = Fe3+, Cr3+, Mn2+, and Ni2+) were then introduced by cation exchange method, and their effects on the electrocatalytic activity of Co4S3/Co9S8 nanosheets in alkaline media were investigated. The results showed that the doped M-Co4S3/Co9S8 nanosheets exhibited different electrocatalytic properties, mainly due to the charge redistribution caused by the electronic interaction between the dopant metal ions and Co4S3/Co9S8 nanosheets.

CHINESE CHEMICAL LETTERS (2022)

Article Chemistry, Physical

A Cu3P@NiFe-MOF Hybrid as an Efficient Electrocatalyst for Hydrogen and Oxygen Evolution Reactions

Erlei Li et al.

Summary: In this study, an efficient and durable electrocatalyst consisting of Cu3P@NiFe-MOF was synthesized, which shows great potential to replace noble metal materials in hydrogen and oxygen evolution reactions.

CATALYSIS LETTERS (2022)

Article Chemistry, Physical

Predicted superior hydrogen evolution activities of MoC via surface dopant

Guang-Qiang Yu et al.

Summary: This work investigates the effect of surface doping on the hydrogen evolution reaction (HER) activity of molybdenum carbides (MoC) using density functional theory (DFT). The study demonstrates that specific doping ranges can enhance the HER activity of MoC by modifying the hydrogen adsorption ability and charge redistribution.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Chemistry, Applied

Metal-organic frameworks derived transition metal phosphides for electrocatalytic water splitting

Li-Ming Cao et al.

Summary: The article discusses the use of metal-organic frameworks (MOFs) as molecular platforms for the design of reactive transition metal phosphides (TMPs) as electrocatalysts for water splitting. It highlights the improvement of intrinsic activity through modulating the electronic structure of the catalysts and the protection provided by a carbon layer formed from organic ligands. The incorporation of heteroatom-containing ligands also allows for the regulation of coordination microenvironments and electronic structures of the active centers. The article summarizes the latest developments in MOF-derived TMPs and identifies scientific challenges in designing advanced TMP-based electrocatalysts, while also providing an outlook for future research.

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Article Chemistry, Physical

Impact of an Incompatible Atomic Nickel-Incorporated Metal-Organic Framework on Phase Evolution and Electrocatalytic Activity of Ni-Doped Cobalt Phosphide for the Hydrogen Evolution Reaction

Paulraj Arunkumar et al.

Summary: The development of efficient and durable electrocatalysts for sustainable hydrogen production is highly desired. In this study, a highly efficient bimetallic phosphide electrocatalyst is developed by designing a metal-organic framework (MOF) as a precursor. The incorporation of nickel modulates the pore structure and surface chemistry of the catalyst, while the phosphidation process achieves phase engineering through enhanced diffusion. The resulting bimetallic phosphide electrocatalyst exhibits superior hydrogen evolution activity.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Physical

MOF-derived formation of ultrafine FeP nanoparticles confined by N/P Co-doped carbon as an efficient and stable electrocatalyst for hydrogen evolution reaction

Ting Zhang et al.

Summary: This study presents a simple method for synthesizing N/P co-doped carbon encapsulated ultrafine FeP nanoparticles (FeP@NPC) for the hydrogen evolution reaction (HER). The optimized FeP@NPC exhibits outstanding HER activity and stability, attributed to the ultrafine FeP nanoparticles and N/P co-doped carbon. The combination of FeP nanoparticles with N/P co-doped carbon also protects the FeP nanoparticles from oxidation, ensuring their high stability.

APPLIED SURFACE SCIENCE (2022)

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A MOF-based Ultra-Strong Acetylene Nano-trap for Highly Efficient C2H2/CO2 Separation

Zheng Niu et al.

Summary: A new type of ultra-strong C2H2 nano-trap has been proposed, which efficiently captures C2H2 molecules and separates C2H2/CO2 mixture based on multiple binding interactions. The nano-trap exhibits high C2H2 uptake, selectivity, and the locations of C2H2 molecules within it have been visualized by in situ single-crystal X-ray diffraction studies, identifying multiple binding sites responsible for the strong interactions with C2H2.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Ultrasmall Mo2C in N-doped carbon material from bimetallic ZnMo-MOF for efficient hydrogen evolution

Yuanyuan Guo et al.

Summary: A convenient approach was proposed to synthesize ultrafine Mo2C nanoparticles embedded in hierarchically porous N-doped carbon material to obtain ZnMo-MI-1000, which demonstrated satisfying HER performance. The multiporous network of ZnMo-MI-1000 provides effective electrocatalytic kinetics in both acidic and alkaline media, serving as a highly active and durable nonprecious metal electrocatalyst for HER.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Physical

Tuning the morphology and electron structure of metal-organic framework-74 as bifunctional electrocatalyst for OER and HER using bimetallic collaboration strategy

Cheng Chen et al.

Summary: 2D NiFe-MOF-74 nanosheets on nickel foam exhibit increased surface area, efficient utilization of active metal sites, and enhanced electrocatalytic activity through the collaboration of Ni and Fe metals, making them promising for water-splitting applications.

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Ultrathin Ti2NTx MXene-wrapped MOF-derived CoP frameworks towards hydrogen evolution and water oxidation

Hui Zong et al.

Summary: The Ti2NTx@MOF-CoP composite is a low-cost, high-activity bifunctional catalyst with competitive hydrogen evolution performance in a wide pH range. Setting a dual-electrode configuration based on its bifunctional activity in alkaline conditions can achieve impressive catalytic stability.

ELECTROCHIMICA ACTA (2021)

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Porous MoWN/MoWC@N-C Nano-octahedrons synthesized via confined carburization and vapor deposition in MOFs as efficient trifunctional electrocatalysts for oxygen reversible catalysis and hydrogen production in the same electrolyte

Chao Feng et al.

Summary: This study utilized a simple MOFs-assisted synthesis strategy to successfully synthesize porous nano-octahedral materials MoWN/MoWC@N-C-800, which exhibited excellent electrocatalytic activity in oxygen reduction reaction, oxygen evolution reaction, and hydrogen evolution reaction. The material showed exceptional cycle stability and durability in an alkaline medium, making it suitable for constructing high-performance zinc-air batteries and driving electrocatalytic water splitting in a self-powered manner. The successful preparation of these materials provides new reference ideas for developing functional materials with high catalytic properties for various applications.

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A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture

Jian-Bin Lin et al.

Summary: Zinc-based CALF-20 demonstrates high efficiency and cost-effectiveness in CO2 capture, with the ability to resist water interference, low regeneration cost, and strong durability.

SCIENCE (2021)

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A-Site Management Prompts the Dynamic Reconstructed Active Phase of Perovskite Oxide OER Catalysts

Yu Sun et al.

Summary: Perovskite oxides, with a refined A-site management strategy, can enhance OER performance through promoting the surface reconstruction of the active phase. The A-site Ce doping in particular shows a strong correlation with the dynamic structure-activity relationship during OER, providing insights for accurate design of high-efficiency perovskite OER electrocatalysts.

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Hydrogen production from water electrolysis: role of catalysts

Shan Wang et al.

Summary: Hydrogen is a promising substitute for fossil fuels as a clean and renewable energy source. Efficient hydrogen production is a key challenge, with catalysis and electrocatalysis playing a critical role in achieving this goal.

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Reversing cold tumors to hot: An immunoadjuvant-functionalized metal-organic framework for multimodal imaging-guided synergistic photoimmunotherapy

Zhijin Fan et al.

Summary: This study constructed a multimodal imaging-guided synergistic cancer photoimmunotherapy using metal-organic frameworks, achieving GSH-controlled release of immunoadjuvants and activating the immune system to significantly enhance tumor cytotoxicity, leading to high cure rates.

BIOACTIVE MATERIALS (2021)

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Designing MOF Nanoarchitectures for Electrochemical Water Splitting

Ben Zhang et al.

Summary: This paper presents the most pivotal advances in engineering MOF nanoarchitectures for efficient electrochemical water splitting. It summarizes the design of catalytic centers for MOF-based/derived electrocatalysts and discusses breakthroughs in catalytic activities, identification of highly active sites, and fundamental mechanisms. Additionally, it provides comprehensive commentary on current primary challenges and future perspectives in water splitting and its commercialization for hydrogen production.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

MIL-101-Derived Mesoporous Carbon Supporting Highly Exposed Fe Single-Atom Sites as Efficient Oxygen Reduction Reaction Catalysts

Xiaoying Xie et al.

Summary: Fe single-atom catalysts with atomic FeNx active sites show great promise as alternatives to platinum-based catalysts for the oxygen reduction reaction. This study utilized a mesoporous MOF NH2-MIL-101(Al) as a precursor to prepare a series of N-doped carbon supports with well-defined mesoporous structure at different pyrolysis temperatures. The resulting Fe SAC-MIL101-T catalysts showed outstanding ORR activity in alkaline media and excellent performance in zinc-air batteries.

ADVANCED MATERIALS (2021)

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A review of synthesis strategies for MOF-derived single atom catalysts

Jongkook Hwang

Summary: Single atom catalysts (SACs) have emerged as a promising class of catalysts that combine the advantages of both heterogeneous and homogeneous catalysts, offering high atom utilization efficiency, unprecedentedly high catalytic activity and selectivity. Metal-organic framework (MOF)-derived synthesis routes, with their high structural/chemical tunability, large surface area and high porosity, have shown great potential for preparing stable SACs without particle aggregation and sintering. This review comprehensively summarizes the synthesis strategies for MOF-derived SACs, categorizing them into five classes and discussing the current challenges and future opportunities in this field.

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2021)

Article Chemistry, Applied

MOF-derived Co-MOF,O-doped carbon as trifunctional electrocatalysts to enable highly efficient Zn-air batteries and water-splitting

Xinde Duan et al.

Summary: The study demonstrated a facile strategy to synthesize a novel Co-MOF-O-doped carbon catalyst with superior ORR, OER, and HER activities, showing great potential for high-performance Zn-air batteries and overall water splitting.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Ultrahigh-Pressure Preparation and Catalytic Activity of MOF-Derived Cu Nanoparticles

Ichiro Yamane et al.

Summary: A study on processing Cu-benzenetricarboxylic acid metal-organic framework under ultrahigh pressure and high temperature revealed that the decomposition temperature of the MOF significantly decreased at 5 GPa, resulting in smaller Cu nanoparticles obtained in a carbon matrix. Catalytic activity tests for Huisgen cycloaddition showed that the sample processed at 5 GPa exhibited better performance compared to those prepared without high pressure.

NANOMATERIALS (2021)

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Exposing unsaturated Cu1-O2 sites in nanoscale Cu-MOF for efficient electrocatalytic hydrogen evolution

Weiren Cheng et al.

Summary: We have developed a promising electrocatalyst composed of Fe(OH)(x)@Cu-MOF nanoboxes, which exhibit superior activity and stability for the electrocatalytic hydrogen evolution reaction.

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The Significance of Properly Reporting Turnover Frequency in Electrocatalysis Research

Sengeni Anantharaj et al.

Summary: Turnover frequency (TOF) has long been used as an accurate indicator of the intrinsic activity of catalysts in electrocatalytic reactions, but is often not properly reported. While current density is significant in determining apparent activity, TOF can more accurately reflect intrinsic activity free from interfering phenomena, yet remains underused in electrocatalysis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Stability of ZIF-8 nanopowders in bacterial culture media and its implication for antibacterial properties

Mahdiar Taheri et al.

Summary: The study demonstrates the superior antibacterial property of zinc-based MOF, ZIF-8, against gram-negative Escherichia coli due to its enhanced degradation in bacterial culture media, despite the commonly held belief of its stability in aqueous media. The results emphasize the importance of stability studies on MOFs for their biomedical applications in terms of efficacy, biosafety, and eco-safety.

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Article Chemistry, Physical

A novel detection method for organophosphorus insecticide fenamiphos: Molecularly imprinted electrochemical sensor based on core-shell Co3O4@MOF-74 nanocomposite

Hassan Karimi-Maleh et al.

Summary: A novel molecularly imprinted electrochemical sensor for the detection of organophosphorus insecticide fenamiphos (FEN) was successfully developed in this study. The sensor, based on Co3O4 nanowire and core-shell Co3O4@MOF-74 nanocomposite, demonstrated high selectivity, stability, and reproducibility.

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MOF-derived cobalt phosphide as highly efficient electrocatalysts for hydrogen evolution reaction

Donghong Duan et al.

Summary: In this study, Co-based metal-organic framework was used as the precursor to prepare two types of cobalt phosphide catalysts, which showed good electrochemical performance for hydrogen evolution reactions in acid electrolyte. The Di-CoP/C catalyst exhibited lower overpotential and Tafel slope, as well as excellent stability.

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Optimizing Hydrogen Storage in MOFs through Engineering of Crystal Morphology and Control of Crystal Size

Kuthuru Suresh et al.

Summary: By improving packing efficiency and crystal size distributions, the hydrogen storage density of metal-organic frameworks (MOFs) can be significantly enhanced, maximizing storage capacity. System model projections show that engineering crystal morphology/size or using bimodal distributions of cubic crystal sizes can surpass the current volumetric capacity of compressed storage systems.

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Alkaline Water Splitting Enhancement by MOF-Derived Fe-Co-Oxide/Co@NC-mNS Heterostructure: Boosting OER and HER through Defect Engineering and In Situ Oxidation

Thangjam Ibomcha Singh et al.

Summary: The development of a new type of freestanding, defect-rich mixed-metal oxide/hydroxide heterostructure was reported, showing excellent bifunctional properties with low overpotentials for both oxygen evolution reaction and hydrogen evolution reaction at a current density of 10 mA cm(-2).
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Surface reconstruction of CoO (111) and its effects on the formation of oxygen vacancy and OER activity

Ning Ma et al.

Summary: The study reveals that surface reconstruction of CoO (111) enhances OER activity and stability of VO, leading to changes in electron accumulation, bonding state between Co and O atoms, and adsorption of OH. The findings provide a theoretical basis for the design and application of Co-based OER catalysts.

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Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4

Jian Li et al.

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A novel and efficient method of MOF-derived electrocatalyst for HER performance through doping organic ligands

Ling Qin et al.

Summary: In this study, a highly stable and active Co/NC@PMDA material was successfully synthesized via solvothermal synthesis, demonstrating excellent electrocatalytic hydrogen evolution performance. The research also showed that doping organic ligands can enhance the catalytic performance of the material.

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Sunil M. Galani et al.

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Study of CoCu Alloy Nanoparticles Supported on MOF-Derived Carbon for Hydrosilylation of Ketones

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