期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 76, 页码 11401-11404出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc03532h
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The development of a new catalytic and straightforward strategy for constructing C-N bonds is important in synthetic chemistry. In this study, we present a photocatalysed protocol for direct C-H amidation of indoles using a rationally designed tert-butyl alkyl((perfluoropyridin-4-yl)oxy)carbamate. A range of biologically significant aminoindoles were synthesized under mild conditions with excellent regioselectivity and broad substrate scope.
Development of a new catalytic and straightforward strategy to construct C-N bonds is playing a pivotal role in synthetic chemistry. Here, we report a photocatalysed protocol to access direct C-H amidation of indoles, enabled by a rationally designed tert-butyl alkyl((perfluoropyridin-4-yl)oxy)carbamate. A series of biologically important aminoindoles were prepared under mild conditions with excellent regioselectivity and broad substrate scope.
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