☆ 4.7 Article

Recent advances in electrocatalytic ammonia synthesis

CHINESE JOURNAL OF CATALYSIS (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。
Review Chemistry, Physical

Single transition metal atom anchored on g-C3N4 as an electrocatalyst for nitrogen fixation: A computational study

Nan Zhang et al.

Summary: Electrocatalytic nitrogen reduction reaction (NRR) is an environmentally friendly and sustainable method to produce ammonia at room temperature. In this study, single V atoms anchored on g-C3N4 were identified as highly efficient electrocatalysts for NRR. The superior NRR performance of V@g-C3N4 is attributed to the peculiar electronic structure of V in the six-fold cavity of g-C3N4 and its role as a good electron transmitter between NxHy species and g-C3N4. The thermodynamic and electrochemical stability of V@g-C3N4 indicate its feasibility for experimental synthesis. This work contributes to the development of noble metal-free NRR electrocatalysts and ambient artificial nitrogen fixation.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

添加到收藏夹
Article Chemistry, Physical

Boosting electrochemical nitrate-to-ammonia conversion by self- supported MnCo2O4 nanowire array

Jun Li et al.

Summary: In this study, a self-supported spinel-type MnCo2O4 nanowire array was demonstrated to efficiently catalyze the conversion of NO3- to NH3 under ambient conditions, achieving excellent electrocatalytic performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

添加到收藏夹
Article Chemistry, Physical

Selenium-vacancy-rich WSe2 for nitrate electroreduction to ammonia

Peng Shen et al.

Summary: The study demonstrates that Se-vacancy-rich WSe2 nanoplatelets are highly efficient catalysts for electrocatalytic nitrate reduction to ammonia (NO3RR). The introduction of Se-vacancy activates nitrate and reduces the reaction barriers, promoting the nitrate reduction process.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

添加到收藏夹
Article Chemistry, Physical

Unveiling selective nitrate reduction to ammonia with Co3O4 nanosheets/TiO2 nanobelt heterostructure catalyst

Xiaoya Fan et al.

Summary: In this study, a novel NO3RR electrocatalyst, Co3O4@TiO2/TP, was reported to exhibit excellent Faradaic efficiency and high NH3 yield, as well as strong electrochemical durability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

添加到收藏夹
Article Nanoscience & Nanotechnology

A High-Throughput Screening toward Efficient Nitrogen Fixation: Transition Metal Single-Atom Catalysts Anchored on an Emerging π-π Conjugated Graphitic Carbon Nitride (g-C10N3) Substrate with Dirac Dispersion

Qiang Zhang et al.

Summary: TM-Nx is a promising catalyst for green ammonia synthesis, leading to increased interest in single-atom catalysts for nitrogen fixation. In this study, a holey graphitic carbon-nitride skeleton was constructed, which provides excellent electrical conductivity for high-efficiency nitrogen reduction reaction (NRR). The calculations showed that tungsten embedded in the graphitic carbon-nitride substrate exhibited optimal NRR behavior, with a suppressed hydrogen evolution reaction and low energy cost. Overall, this research provides valuable insights for the design of efficient catalysts for nitrogen fixation.

ACS APPLIED MATERIALS & INTERFACES (2023)

添加到收藏夹
Article Chemistry, Physical

Ambient ammonia synthesis via nitrite electroreduction over NiS2 nanoparticles-decorated TiO2 nanoribbon array

Xun He et al.

Summary: Nitrite (NO2-), a nitrogen-containing pollutant, is widely present in aqueous solution and causes environmental and health problems. Electro-catalytic reduction of NO2- is a promising and sustainable method to remove NO2- and produce valuable ammonia (NH3). In this study, NiS2 nanoparticles decorated TiO2 nanoribbon array on titanium mesh (NiS2@TiO2/TM) is reported as an excellent electrocatalyst for ambient NH3 synthesis through NO2- reduction reaction (NO2-RR). NiS2@TiO2/TM demonstrates a satisfactory NH3 yield of 591.9 lmol h-1 cm-2 and a high Faradaic efficiency of 92.1% when tested in NO2--containing solution. Additionally, it exhibits remarkable stability during a 12-hour electrolysis test.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

添加到收藏夹
Article Chemistry, Physical

Electro-triggered Joule heating method to synthesize single-phase CuNi nano -alloy catalyst for efficient electrocatalytic nitrate reduction toward ammonia

Zunjie Zhang et al.

Summary: The study successfully synthesized a CuNi nano-alloy catalyst uniformly dispersed on carbon fiber paper through an electrotriggered Joule heating method, which exhibited higher electrocatalytic activity for nitrate reduction reaction than pure copper nanoparticles. The catalyst showed high efficiency in the reduction of nitrate towards ammonia.

NANO RESEARCH (2023)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-efficiency electroreduction of nitrite to ammonia on a Cu@TiO2 nanobelt array

Ling Ouyang et al.

Summary: In this study, a high-efficiency electrocatalyst Cu@TiO2/TP was reported for NO2- reduction to produce high-value ammonia (NH3). The Cu@TiO2/TP catalyst exhibited outstanding catalytic performance in neutral solution, with a high NH3 yield (760.5 mu mol h(-1) cm(-2)) and excellent faradaic efficiency (95.3%). It also demonstrated good electrochemical stability during cyclic tests and long-term electrolysis.

CHEMICAL COMMUNICATIONS (2023)

添加到收藏夹
Article Chemistry, Physical

Electro-triggered Joule heating method to synthesize single-phase CuNi nano-alloy catalyst for efficient electrocatalytic nitrate reduction toward ammonia

Zunjie Zhang et al.

Summary: By using the electrotriggered Joule heating method, a uniformly dispersed single-phase CuNi nano-alloy catalyst was synthesized, which showed high electrocatalytic activity for the nitrate reduction reaction and efficient ammonia production. Theoretical calculations revealed that alloying Cu with Ni enhanced the adsorption of NO3- and weakened the adsorption of NH3, while also suppressing the competitive adsorption of hydrogen ions.

NANO RESEARCH (2023)

添加到收藏夹
Article Chemistry, Multidisciplinary

Co-NCNT nanohybrid as a highly active catalyst for the electroreduction of nitrate to ammonia

Jie Chen et al.

Summary: Electrocatalytic nitrate reduction to produce ammonia is an attractive method for environmental mitigation. This study introduces a highly active Co-NCNT nanohybrid catalyst for efficient ammonia synthesis in alkaline solution, demonstrating excellent electrochemical stability.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

A TiO2-x nanobelt array with oxygen vacancies: an efficient electrocatalyst toward nitrite conversion to ammonia

Donglin Zhao et al.

Summary: This study reports that a TiO2-x nanobelt array with oxygen vacancies can convert nitrite into ammonia with high electrocatalytic efficiency and yield in alkaline solution.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Boosting electrochemical nitrite-ammonia conversion properties by a Cu foam@Cu2O catalyst

Qiuyue Chen et al.

Summary: In this study, Cu2O particles self-supported on Cu foam with enriched oxygen vacancies were developed as efficient catalysts for selective reduction of nitrite to ammonia. The catalyst exhibited a high NH3 yield rate and Faradaic efficiency under experimental conditions, providing a new approach for rational design of Cu-based catalysts for NH3 electrosynthesis.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Recent advances in electrocatalytic nitrite reduction

Xi Zhang et al.

Summary: This review highlights the recent progress and applications of electrochemical nitrite reduction, including the preparation of gaseous and liquid products, catalyst selection, and understanding of reaction mechanisms. The challenges and opportunities in this field are analyzed as well.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Elucidating the activity, mechanism and application of selective electrosynthesis of ammonia from nitrate on cobalt phosphide

Shenghua Ye et al.

Summary: This study found that phosphorus plays a crucial role in stabilizing the active phase and optimizing the energy barriers of nitrate reduction reaction, while Co 4p orbitals were directly involved in the nitrate adsorption and electron transfer step. Additionally, cobalt phosphide nanosheet arrays grown on carbon fiber cloth exhibited high ammonia-evolving rate and Faraday efficiency under alkaline conditions.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

Ni2P nanosheet array for high-efficiency electrohydrogenation of nitrite to ammonia at ambient conditions

Guilai Wen et al.

Summary: Ammonia plays a crucial role in agriculture and industry, but its traditional production methods suffer from environmental pollution and high energy consumption. This study introduces a highly efficient electrocatalyst that can convert nitrite into ammonia at room temperature, achieving high yield rates and selectivity.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

High-Throughput Screening of Efficient Biatom Catalysts Based on Monolayer Carbon Nitride for the Nitric Oxide Reduction Reaction

Yanmei Zang et al.

Summary: Efficient catalysts for direct NO-to-NH3 conversion are explored using high-throughput first-principles calculations. A promising biatom catalyst (BAC) of Cr-2-C2N is screened out, showing high stability, activity, and selectivity for NORR toward NH3 synthesis. This study also identifies the effective descriptors for efficient NORR catalysts.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrochemical Reduction of Gaseous Nitrogen Oxides on Transition Metals at Ambient Conditions

Byung Hee Ko et al.

Summary: This research demonstrates a method of reducing gaseous NOx emissions at ambient temperatures through an electrochemical pathway. The study found that copper has a high selectivity towards NH3 formation, and a high NO coverage facilitates the N-N coupling reaction. This work provides a promising avenue for reducing gaseous NOx emissions at ambient conditions using renewable electricity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹
Article Chemistry, Physical

In situ grown Fe3O4 particle on stainless steel: A highly efficient electrocatalyst for nitrate reduction to ammonia

Xiaoya Fan et al.

Summary: This work presents Fe3O4/SS as an efficient electrocatalyst for NO3- reduction to NH3, achieving high Faradaic efficiency and NH3 yield in NaNO3 and NaOH solution, with robust structural and electrochemical stability. The study provides valuable insights for expanding the application of metallic oxide electrocatalysts in NH3 synthesis, supported by theoretical calculations uncovering the catalytic mechanism.

NANO RESEARCH (2022)

添加到收藏夹
Article Chemistry, Physical

Biomass Juncus derived carbon decorated with cobalt nanoparticles enables high-efficiency ammonia electrosynthesis by nitrite reduction

Jiaqian Wang et al.

Summary: In this study, cobalt nanoparticle decorated biomass Juncus derived carbon was developed as a highly active NO2RR catalyst with high durability. The catalyst exhibited high NH3 yield and faradaic efficiency in alkaline media.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹
Article Chemistry, Physical

Amorphization engineered VSe2-x nanosheets with abundant Se-vacancies for enhanced N2 electroreduction

Yaojing Luo et al.

Summary: In this study, the structural regulation of VSe2 through amorphization engineering led to the development of amorphous VSe2-x nanosheets with enriched Se-vacancies, resulting in significantly enhanced NRR activity. These amorphous VSe2-x nanosheets exhibited high NH3 yield and faradaic efficiency in NH3 synthesis, outperforming their crystalline counterparts.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Efficient nitric oxide electroreduction toward ambient ammonia synthesis catalyzed by a CoP nanoarray

Jie Liang et al.

Summary: The ever-increasing anthropic NO emission has caused severe environmental issues. Electrochemical reduction of NO has emerged as a promising approach for sustainable NO abatement and NH3 synthesis, but requires highly active and selective electrocatalysts. In this study, a CoP nanowire array on Ti mesh was used as an efficient catalyst for converting NO to NH3. This catalyst demonstrated excellent activity, selectivity, durability, and was also used as a cathode catalyst for a Zn-NO battery.

INORGANIC CHEMISTRY FRONTIERS (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Ambient electrochemical N2-to-NH3 conversion catalyzed by TiO2 decorated juncus effusus-derived carbon microtubes

Haijun Chen et al.

Summary: In this study, a hybrid catalyst of TiO2 and juncus effusus-derived carbon microtubes with a three-dimensional cross-linked hollow tubular structure is proposed for efficient electrocatalytic conversion of N-2 to NH3 at ambient conditions. The catalyst shows a high NH3 yield and faradaic efficiency in 0.1M Na2SO4, along with superior electrochemical and structural stability.

INORGANIC CHEMISTRY FRONTIERS (2022)

添加到收藏夹
Article Chemistry, Physical

Electro-synthesis of Ammonia from Dilute Nitric Oxide on a Gas Diffusion Electrode

Seonjeong Cheon et al.

Summary: The electrochemical conversion of nitric oxide (NO) to ammonia (NH3) offers a sustainable route to transform air pollutants into value-added chemicals. By incorporating nanoscale zero-valent iron into a gas diffusion electrode (GDE), a high NH3 production rate and efficiency can be achieved. Controlling the proton concentration in the electrolyte further accelerates the NH3 production rate.

ACS ENERGY LETTERS (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

High-Performance Electrochemical Nitrate Reduction to Ammonia under Ambient Conditions Using a FeOOH Nanorod Catalyst

Qin Liu et al.

Summary: This study introduces a high-performance electrocatalyst FeOOH/CP, which efficiently converts nitrate to ammonia at room temperature, with high ammonia yield and remarkably high Faradic efficiency.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Defect engineering for high-selection-performance of NO reduction to NH3 over CeO2 (111) surface: A DFT study

Chaozheng He et al.

Summary: To reduce the greenhouse effect and develop future energy carriers, efficient, controllable, and highly sensitive catalytic materials are crucial. This study proposes the use of nitric oxide (NO) as a supplement for ammonia synthesis and investigates the potential of CeO2 (111) nanosheets with La doping and oxygen vacancy for NO capture and hydrogenation. The results show promising performance for the reduction of NO and synthesis of ammonia at room temperature.

CHINESE CHEMICAL LETTERS (2022)

添加到收藏夹
Article Materials Science, Ceramics

Ultrafine Cu nanoparticles decorated porous TiO2 for high-efficient electrocatalytic reduction of NO to synthesize NH3

Lei Chen et al.

Summary: This study reports a binary catalyst Cu/P-TiO2 for low-temperature electrocatalytic reduction of nitric oxide (NORR). The catalyst takes advantages of Cu electrocatalysts and porous TiO2, exhibiting excellent electrocatalytic activity and high Faraday efficiency.

CERAMICS INTERNATIONAL (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Enhancing Electrocatalytic NO Reduction to NH3by the CoS Nanosheet with Sulfur Vacancies

Longcheng Zhang et al.

Summary: In this study, it was demonstrated that CoS nanosheets with sulfur vacancies (CoS1-x) act as efficient catalysts for the electrochemical conversion of NO to NH3, exhibiting high production rate and Faradaic efficiency. The Zn-NO battery with CoS1-x showed excellent performance, indicating its potential application in nitrogen oxide conversion.

INORGANIC CHEMISTRY (2022)

添加到收藏夹
Article Chemistry, Physical

Iron-doped cobalt oxide nanoarray for efficient electrocatalytic nitrate-to-ammonia conversion

Peipei Wei et al.

Summary: In this study, Fe-doped Co3O4 nanoarray is reported to efficiently catalyze NO3RR for NH3 production in neutral conditions, achieving high yield and Faradaic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

Cu nanoparticles decorated juncus-derived carbon for efficient electrocatalytic nitrite-to-ammonia conversion

Ling Ouyang et al.

Summary: This work proposes a high-active catalyst, Cu nanoparticles decorated juncus-derived carbon, for the conversion of nitrite to ammonia, achieving high Faradaic efficiency and satisfactory yield. The study also provides insightful understanding of the internal catalytic mechanism through computational calculations.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

High-efficiency NO electroreduction to NH3 over honeycomb carbon nanofiber at ambient conditions

Ling Ouyang et al.

Summary: In this study, a metal-free catalyst consisting of honeycomb carbon nanofiber coated on carbon paper was developed for efficient electroreduction of NO to NH3 in ambient conditions. The catalyst exhibited high NH3 yield and Faradaic efficiency, as well as excellent stability. Theoretical calculations suggested that the -OH group served as the most active site for NO reduction, with a low energy barrier for the potential-determining step.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

Ambient ammonia production via electrocatalytic nitrite reduction catalyzed by a CoP nanoarray

Guilai Wen et al.

Summary: In this study, ambient ammonia production via electrochemical nitrite (NO2-) reduction catalyzed by a CoP nanoarray on titanium mesh (CoP NA/TM) is demonstrated. The catalyst showed a high NH3 yield and Faradaic efficiency in alkaline solution, presenting a potential alternative to industrial ammonia production.

NANO RESEARCH (2022)

添加到收藏夹
Article Chemistry, Physical

Enhancing electrocatalytic N2-to-NH3 fixation by suppressing hydrogen evolution with alkylthiols modified Fe3P nanoarrays

Tong Xu et al.

Summary: The study introduces a hydrophobic thiol-modified Fe3P nanoarray catalyst, which enhances the N-2 electroreduction activity and NH3 yield. The catalyst shows high efficiency and stability in 0.1 M Na2SO4.

NANO RESEARCH (2022)

添加到收藏夹
Article Chemistry, Physical

Bi nanoparticles/carbon nanosheet composite: A high-efficiency electrocatalyst for NO reduction to NH3

Qian Liu et al.

Summary: By developing Bi nanoparticles/carbon nanosheet composite as a catalyst, highly efficient NO reduction and selective NH3 formation can be achieved.

NANO RESEARCH (2022)

添加到收藏夹
Article Chemistry, Physical

FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions

Jie Liang et al.

Summary: This paper introduces an FeP nanorod array on carbon cloth as an efficient catalyst for NO electroreduction to NH3. Under experimental conditions, the catalyst exhibits low onset potential, high Faradaic efficiency, and large NH3 yield, while maintaining good stability. Furthermore, the catalytic mechanism of the catalyst is investigated through theoretical calculations.

NANO RESEARCH (2022)

添加到收藏夹
Editorial Material Multidisciplinary Sciences

Electrochemical nitrate reduction to ammonia on copper-based materials for nitrate-containing wastewater treatment

Yancai Yao et al.

SCIENCE BULLETIN (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

High-Efficiency Electrosynthesis of Ammonia with Selective Reduction of Nitrate in Neutral Media Enabled by Self-Supported Mn2CoO4 Nanoarray

Lisi Xie et al.

Summary: This study discovers that electroreduction of nitrate is an efficient method for the synthesis of environmentally friendly ammonia gas. The researchers find that the Mn(2)CoO(4) nanoarray grown on carbon cloth serves as an excellent electrocatalyst with high ammonia production efficiency and stability.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

Cu/CuOx In-Plane Heterostructured Nanosheet Arrays with Rich Oxygen Vacancies Enhance Nitrate Electroreduction to Ammonia

Hongjing Wang et al.

Summary: A high-performance catalyst Cu/CuOx/CF for ammonia synthesis has been studied, which enhances the conversion rate and selectivity of nitrate to ammonia through the construction of oxygen-deficient Cu/CuOx supported by Cu foam.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Review Chemistry, Multidisciplinary

Electrocatalytic conversion of nitrate waste into ammonia: a review

Jayaraman Theerthagiri et al.

Summary: This article reviews the electrocatalytic conversion of nitrate waste into ammonia, focusing on catalysts, reaction conditions, and side reactions. Electrocatalysts with transition metals facilitate electron transfer, while carbon-based materials enable green electro-conversion. The results show high nitrate conversion rates and ammonia selectivity.

ENVIRONMENTAL CHEMISTRY LETTERS (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

High-Efficiency Ammonia Electrosynthesis on Anatase TiO2-x Nanobelt Arrays with Oxygen Vacancies by Selective Reduction of Nitrite

Zhaofei Ren et al.

Summary: Electrocatalytic reduction of nitrite to NH3 can be efficiently achieved using oxygen vacancy-rich A-TiO2-x nanoarray as a superb catalyst, which exhibits excellent catalytic performance and durability. Additionally, this nanoarray can be applied in Zn-NO2- batteries, delivering high power density and NH3 yield.

INORGANIC CHEMISTRY (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia

Ji Yang et al.

Summary: This study reveals the restructuring of the as-synthesized Cu-N4 single-atom site to nanoparticles during the electrochemical reduction of nitrate to ammonia. The restructuring and the enhancement of the ammonia production rate occur concurrently with the applied potential switching. The Cu nanoparticles are found to be the genuine active sites for nitrate reduction to ammonia.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹
Article Chemistry, Physical

Enhanced N2-to-NH3 conversion efficiency on Cu3P nanoribbon electrocatalyst

Qian Liu et al.

Summary: Cu3P nanoribbon is proposed as a highly efficient electrocatalyst for the conversion of nitrogen to ammonia. It shows excellent catalytic performance and stability under benign conditions and achieves high Faradaic efficiency and large yield.

NANO RESEARCH (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

In Situ Growth of Fe2O3 Nanorod Arrays on Carbon Cloth with Rapid Charge Transfer for Efficient Nitrate Electroreduction to Ammonia br

Tingsong Li et al.

Summary: This article presents an efficient catalyst for electrochemical reduction of nitrate to ammonia. The in situ growth of Fe2O3 nanorod arrays on carbon cloth provides abundant active sites and fast electron transport, resulting in a high NH3 yield rate. The catalytic mechanism of nitrate to NH3 is revealed using in situ Raman spectroscopy and attenuated total reflection Fourier transform infrared spectroscopy.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

High-Efficiency Electrochemical Nitrate Reduction to Ammonia on a Co3O4 Nanoarray Catalyst with Cobalt Vacancies

Zhiqin Deng et al.

Summary: This study demonstrates that Co3O4 nanosheet array with cobalt vacancies can enhance the efficiency of nitrate reduction reaction and achieve carbon-free ammonia synthesis with high yield.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Article Nanoscience & Nanotechnology

In Situ Derived Co2B Nanosheet Array: A High-Efficiency Electrocatalyst for Ambient Ammonia Synthesis via Nitrate Reduction

Lisi Xie et al.

Summary: This study presents a method for efficient NH3 synthesis under ambient conditions through in situ derivation of an amorphous Co2B layer on a Co3O4 nanosheet array on a Ti mesh. The Co2B@Co3O4/TM material exhibits excellent catalytic performance, with a maximum Faradaic efficiency of 97.0% and a remarkable NH3 yield of 8.57 mg/h/cm(2), along with durability for stable NO3--to-NH3 conversion over multiple recycling tests and electrolysis duration. The material also shows potential as an efficient cathode material for Zn-NO3- batteries, enabling NH3 production alongside electricity generation. The catalytic mechanisms are further explored through theoretical calculations.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Co Nanoparticles Decorated Corncob-Derived Biomass Carbon as an Efficient Electrocatalyst for Nitrate Reduction to Ammonia

Ting Xie et al.

Summary: This study presents an ecofriendly method for reducing nitrate to ammonia using Co nanoparticles decorated corncob-derived biomass carbon as a highly active catalyst. The catalyst demonstrates remarkable efficiency and yield in alkaline media, and shows excellent durability in long-term and cycle-electrolysis tests.

INORGANIC CHEMISTRY (2022)

添加到收藏夹
Article Chemistry, Physical

Nitrite reduction over Ag nanoarray electrocatalyst for ammonia synthesis

Qian Liu et al.

Summary: In this study, an efficient electrocatalyst consisting of Ag nanoarray and NiO nanosheets array on carbon cloth as support was reported for the selective reduction of nitrite to ammonia. The catalyst exhibited high ammonia yield and Faradaic efficiency in alkaline solution.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Physical

A theoretical descriptor for screening efficient NO reduction electrocatalysts from transition-metal atoms on N-doped BP monolayer

Jie Wu et al.

Summary: This study systematically investigates the potentials of 29 transition-metal atoms anchored on the nitrogen-doped BP monolayer as efficient electrocatalysts for the electrochemical reduction of nitric oxide (NO). The MoN3/BP and IrN3/BP monatomic catalysts are identified as promising candidates for the synthesis of ammonia (NH3) due to their high limiting potentials and rate constants. The electronic analysis reveals the hybridization between the metal orbitals and NO species, leading to the activation of the adsorbed NO. Furthermore, the MoN3/BP and IrN3/BP catalysts exhibit high thermal stabilities and can be easily synthesized using precursor materials. The results provide insights for the design of efficient NORR electrocatalysts and enhance the understanding of the conversion mechanism from NO to NH3.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Co/N-doped carbon nanospheres derived from an adenine-based metal organic framework enabled high-efficiency electrocatalytic nitrate reduction to ammonia

Jie Chen et al.

Summary: This study reports a novel electrocatalyst, Co@NC, with the ability to efficiently synthesize NH3 and high selectivity for NO3- reduction. Under the experimental conditions, Co@NC exhibits a high NH3 yield and excellent electrochemical stability.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Physical

FeS2@TiO2 nanobelt array enabled high-efficiency electrocatalytic nitrate reduction to ammonia

Haipeng Wang et al.

Summary: In this study, FeS2@TiO2 nanoparticles were developed as an electrocatalyst for NO3RR, demonstrating efficient and selective elimination of hazardous NO3- and production of value-added NH3.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

CoS2@TiO2 nanoarray: a heterostructured electrocatalyst for high-efficiency nitrate reduction to ammonia

Xian-En Zhao et al.

Summary: In this study, a CoS2 nanoparticle decorated TiO2 nanobelt array on a titanium plate is reported as an excellent electrocatalyst for the reduction of NO3-. It exhibits high NH3 yield, high faradaic efficiency, and good stability.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Physical

Enhanced electrocatalytic nitrite reduction to ammonia over P-doped TiO2 nanobelt array

Ling Ouyang et al.

Summary: Electrochemical nitrite reduction provides an environmentally friendly method for removing hazardous NO2- and synthesizing sustainable NH3. A P-doped TiO2 nanobelt array supported on titanium plate (P-TiO2/TP) acts as a highly efficient electrocatalyst for the reduction of NO2-, achieving a satisfactory faradaic efficiency of 90.6% and a large NH3 yield of 560.8 mu mol h(-1) cm(-2), surpassing pristine TiO2/TP. In addition, the catalytic mechanism is also revealed through theoretical calculations.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Direct eight-electron NO3--to-NH3 conversion: using a Co-doped TiO2 nanoribbon array as a high-efficiency electrocatalyst

Donglin Zhao et al.

Summary: In this study, a Co-doped TiO2 nanoribbon array was developed as a highly active electrocatalyst for the reduction of NO3- to NH3, achieving a large NH3 yield and high faradaic efficiency, while maintaining strong electrochemical stability.

INORGANIC CHEMISTRY FRONTIERS (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Amorphous CoB nanoarray as a high-efficiency electrocatalyst for nitrite reduction to ammonia

Long Hu et al.

Summary: In this study, an amorphous CoB supported on TiO2 nanoarray was found to be an efficient catalyst for NH3 synthesis through electrochemical reduction of NO2-. It exhibited outstanding yield and high faradaic efficiency.

INORGANIC CHEMISTRY FRONTIERS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Greatly enhanced electrochemical nitrate-to-ammonia conversion over an Fe-doped TiO2 nanoribbon array

Jie Chen et al.

Summary: Fe doping on TiO2 nanoribbon array supported catalyst greatly enhances the electrocatalytic NO3- to NH3 conversion, achieving a high NH3 yield and faradaic efficiency under alkaline conditions. Theoretical calculations show that Fe doping improves electronic conductivity of TiO2 and optimizes adsorption of reactive species on its surface.

GREEN CHEMISTRY (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Ni nanoparticle-decorated biomass carbon for efficient electrocatalytic nitrite reduction to ammonia

Xiuhong Li et al.

Summary: Elecroreduction of NO2- to NH3 is an efficient method for both ammonia synthesis and removal of NO2- pollutants. In this study, Ni nanoparticle-decorated juncus-derived biomass carbon (Ni@JBC-800) is found to be a highly efficient catalyst with a high NH3 yield and large faradaic efficiency in an alkaline electrolyte.

NANOSCALE (2022)

添加到收藏夹
Article Chemistry, Physical

Oxygen vacancies in Co3O4 nanoarrays promote nitrate electroreduction for ammonia synthesis

Xiang Xu et al.

Summary: In this work, an oxygen vacancy-enriched Co3O4 nanosheet array on carbon cloth was demonstrated to be a highly active and stable catalyst for nitrate reduction to ammonia. It exhibited high ammonia yield and selectivity in alkaline solution, as well as excellent stability during long-term electrolysis and application in nitrate-containing wastewater.

SUSTAINABLE ENERGY & FUELS (2022)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Plasma-etched Ti2O3 with oxygen vacancies for enhanced NH3 electrosynthesis and Zn-N2 batteries

Hai-jun Chen et al.

Summary: In this study, a novel electrocatalyst, OV-Ti2O3, was reported for sustainable NH3 production. OV-Ti2O3 exhibited outstanding N-2 fixation performance in experiments and showed excellent performance in the assembled Zn-N-2 battery.

INORGANIC CHEMISTRY FRONTIERS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrocatalytic nitrate reduction to ammonia via amorphous cobalt boride

Yongbin Shi et al.

Summary: By synthesizing CoBx nanoparticles, the study achieved efficient electroreduction of nitrates to produce ammonia. CoBx exhibited high faradaic efficiency and ammonia production rate, attributed to partial electron transfer from B to Co.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Electrochemistry

ITO@TiO2 nanoarray: An efficient and robust nitrite reduction reaction electrocatalyst toward NH3 production under ambient conditions

Shaoxiong Li et al.

Summary: The study reports a three-dimensional catalyst for the reduction of NO2- to produce NH3, demonstrating high activity, excellent selectivity, and durability.

ESCIENCE (2022)

添加到收藏夹
Article Chemistry, Applied

Heterostructuring 2D TiO2 nanosheets in situ grown on Ti3C2Tx MXene to improve the electrocatalytic nitrogen reduction

Xiu Qian et al.

Summary: In this study, TiO2 nanosheets (NSs) grown on highly conductive Ti3C2Tx MXene were proposed to achieve electrocatalytic NH3 synthesis. Ti3C2Tx MXene promoted electron transfer, while in-situ formation of TiO2 NSs prevented stacking and increased surface area. The TiO2/Ti3C2Tx MXene catalyst exhibited high efficiency and strong electrochemical durability, with the nitrogen in the produced NH3 originating from the electrolyte's N2.

CHINESE JOURNAL OF CATALYSIS (2022)

添加到收藏夹
Article Chemistry, Applied

Electrocatalytic ammonia synthesis catalyzed by mesoporous nickel oxide nanosheets loaded with Pt nanoparticles

Wei Xiong et al.

Summary: This study found that the doping of NiO nanosheets with a small amount of Pt nanoparticles significantly improves the Faradaic efficiency and NH3 yield in electrocatalytic nitrogen reduction reaction. It breaks the common perception that commercial Pt-based electrocatalysts have little potential for NRR. The results demonstrate that Pt can be an effective electrochemical catalyst for NRR when loaded on an appropriate substrate and provide a new method for the fabrication of highly active Pt-based NRR electrocatalysts.

CHINESE JOURNAL OF CATALYSIS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

CoO nanoparticle decorated N-doped carbon nanotubes: a high-efficiency catalyst for nitrate reduction to ammonia

Qiru Chen et al.

Summary: This study reports an efficient catalyst, CoO nanoparticle decorated N-doped carbon nanotubes, for the selective hydrogenation of NO3- to NH3, achieving high NH3 yield and faradaic efficiency.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

A 3D FeOOH nanotube array: an efficient catalyst for ammonia electrosynthesis by nitrite reduction

Qin Liu et al.

Summary: In this study, a self-standing FeOOH nanotube array on carbon cloth was proposed as a highly active electrocatalyst for the conversion of nitrite to ammonia. The results showed that the catalyst exhibited high conversion efficiency and ammonia yield, and also demonstrated excellent durability in cyclic and long-term tests.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

Co nanoparticle-decorated pomelo-peel-derived carbon enabled high-efficiency electrocatalytic nitrate reduction to ammonia

Quanying Chen et al.

Summary: In this study, Co nanoparticle-decorated pomelo-peel-derived carbon is demonstrated as an efficient electrocatalyst for nitrate reduction to ammonia, achieving high faradaic efficiency and yield.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Multidisciplinary

A FeCo2O4 nanowire array enabled electrochemical nitrate conversion to ammonia

Jun Li et al.

Summary: A bimetallic FeCo2O4 spinel nanowire array grown on carbon cloth is proposed as an efficient electrocatalyst for the conversion of NO3- to NH3, with high faradaic efficiency and large NH3 yield. It also exhibits excellent stability during electrolysis.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹
Article Chemistry, Physical

Coupling denitrification and ammonia synthesis via selective electrochemical reduction of nitric oxide over Fe2O3 nanorods

Jie Liang et al.

Summary: Direct electrochemical conversion of nitric oxide into ammonia under ambient conditions was achieved using Fe2O3 nanorods as a superb electrocatalyst. The catalyst exhibited a large NH3 yield and high faradaic efficiency in neutral media. The findings suggest the potential for high value-added utilization of industrial gaseous waste and balancing the global nitrogen cycle.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹
Review Chemistry, Multidisciplinary

Electrocatalytic reduction of nitrate - a step towards a sustainable nitrogen cycle

Hui Xu et al.

Summary: Nitrate enrichment poses negative effects on the environment and human health. Traditional techniques for reducing nitrate levels in water bodies have limitations. Electrocatalytic nitrate reduction is a promising method due to its low cost, high efficiency, and environmental friendliness. This article provides a comprehensive account of the principles, methods, challenges, and opportunities in electrocatalytic nitrate reduction.

CHEMICAL SOCIETY REVIEWS (2022)

添加到收藏夹
Review Chemistry, Physical

Iron-group electrocatalysts for ambient nitrogen reduction reaction in aqueous media

Benyuan Ma et al.

Summary: Electrochemical nitrogen reduction reaction has the potential to be an alternative to the industrial Haber-Bosch process for NH3 production due to its low energy consumption and environment friendliness. Iron-group materials show promise as non-noble metal electrocatalysts with cost and performance advantages, but further strategies are needed to improve efficiency and selectivity.

NANO RESEARCH (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Modulating Oxygen Vacancies of TiO2 Nanospheres by Mn-Doping to Boost Electrocatalytic N2 Reduction

Haijun Chen et al.

Summary: TiO2 serves as an active NRR electrocatalyst, and heteroatom doping can enhance its activity to achieve high NH3 yield rate and high Faradaic efficiency.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

添加到收藏夹
Editorial Material Chemistry, Physical

Electrocatalytic Nitrate Reduction for Sustainable Ammonia Production

Phebe H. van Langevelde et al.

Summary: Phebe van Langevelde, Ioannis Katsounaros, and Marc Koper are renowned researchers in the field of electrocatalysis and renewable energy. Their research interests span from fundamental aspects of electrocatalysis to physical electrochemistry and theoretical electrochemistry. They have received various national and international awards for their contributions to the field.

JOULE (2021)

添加到收藏夹
Review Chemistry, Multidisciplinary

The Role of Defects in Metal-Organic Frameworks for Nitrogen Reduction Reaction: When Defects Switch to Features

Islam E. Khalil et al.

Summary: The focus of research is on designing efficient electrocatalysts through defect engineering, with metal-organic frameworks (MOFs) and their derivatives gaining interest for providing more active sites to enhance electrochemical reactions. The paper summarizes in situ characterization techniques for defects, common methods for creating defects in MOFs, recent advances in MOF-based electrocatalysts for NRR, and proposes challenges and outlook for defects in MOFs for NRR.

ADVANCED FUNCTIONAL MATERIALS (2021)

添加到收藏夹
Article Materials Science, Multidisciplinary

Engineering electrocatalyst for low-temperature N-2 reduction to ammonia

Faisal Rehman et al.

Summary: This review summarizes the fundamentals and mechanism of electrochemical nitrogen fixation, with a special focus on the application of 2D materials in electrocatalysts and strategies for achieving high selectivity and activity. It also provides guidance on addressing challenges related to NRR and the impact of environmental contamination.

MATERIALS TODAY (2021)

添加到收藏夹
Article Chemistry, Physical

Theoretical Insights into Superior Nitrate Reduction to Ammonia Performance of Copper Catalysts

Tao Hu et al.

Summary: This study investigated the catalytic performance of nitrate reduction to ammonia on copper crystal surfaces and found that Cu(100) and Cu(111) contribute most to NRA, with different optimal pH conditions. The research clarified the NRA pathway and highlighted the influence of pH on the catalytic processes.

ACS CATALYSIS (2021)

添加到收藏夹
Article Chemistry, Physical

Electrocatalytic Reduction of Nitrate to Ammonia on Low-Cost Ultrathin CoOx Nanosheets

Jing Wang et al.

Summary: The electrochemical nitrate reduction reaction (NITRR) is an attractive method for ammonia synthesis. By designing ultrathin CoOx nanosheets with abundant surface oxygen as catalysts, the efficiency of NITRR can be increased, hydrogen evolution reaction can be suppressed, and the yield of ammonia can be enhanced.

ACS CATALYSIS (2021)

添加到收藏夹
Review Chemistry, Multidisciplinary

Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design

Huidong Shen et al.

Summary: NH3 production currently relies on the energy-intensive Haber-Bosch process, but electrochemical NH3 synthesis powered by renewable electricity offers a promising carbon-neutral and sustainable strategy. However, significant enhancements in energy efficiency, conversion rate, and durability are still needed, achievable only through the design of efficient electrocatalysts.

CHEM (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Boosting Selective Nitrogen Reduction via Geometric Coordination Engineering on Single-Tungsten-Atom Catalysts

Yu Gu et al.

Summary: Studying atomic interface regulation for optimizing single-atom catalysts proves to be a worthwhile research topic, with the successful preparation of a novel W-NO/NC catalyst through the introduction of an oxygen-bridged [WO4] tetrahedron. This catalyst demonstrates excellent selectivity and activity for the electrochemical nitrogen reduction reaction, highlighting the importance of coordination structure in influencing properties.

ADVANCED MATERIALS (2021)

添加到收藏夹
Article Chemistry, Physical

Ammonia and Nitric Acid Demands for Fertilizer Use in 2050

Jeonghoon Lim et al.

Summary: Access to nitrogen-based fertilizers is crucial for maximizing agricultural yield, but the production process contributes significantly to carbon emissions. The market size and value of ammonia and nitric acid will be heavily influenced by the growing global population and food demand over the next three decades. Developing carbon-free technologies for nitrogen and nitrate reduction to meet fertilizer manufacturing demands is essential to address the environmental impact of current production methods.

ACS ENERGY LETTERS (2021)

添加到收藏夹
Article Nanoscience & Nanotechnology

Synergistic Effect of Co(III) and Co(II) in a 3D Structured Co3O4/Carbon Felt Electrode for Enhanced Electrochemical Nitrate Reduction Reaction

Wenyang Fu et al.

Summary: The study demonstrates that by controlling the calcination temperature, a relatively large amount of Co(II) on the surface of the Co3O4/CF electrode (1.3 Co(II)/Co(III) ratio) can be maintained to promote H* formation and enhance the performance of the ENRR. Therefore, building a 3D structure and optimizing the Co(II)/Co(III) ratio are crucial for designing efficient Co3O4 electrocatalysts for ENRR.

ACS APPLIED MATERIALS & INTERFACES (2021)

添加到收藏夹
Article Nanoscience & Nanotechnology

Selective Electrocatalytic Reduction of Nitrate to Ammonia with Nickel Phosphide

Qiufang Yao et al.

Summary: This study reported a method for synthesizing ammonia by electrocatalytic reduction of nitrate using nickel phosphide grown on nickel foam as a cathode. The method showed high yield rate and superior efficiency, achieving high selectivity for ammonia generation through processes such as deoxygenation and hydrogenation.

ACS APPLIED MATERIALS & INTERFACES (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrochemical Nitric Oxide Reduction on Metal Surfaces

Hao Wan et al.

Summary: This study elucidates the selectivity and activity of metal catalysts for NOx electroreduction, with copper showing selective NH3 formation by binding *NO but not *H. Metals that do not bind NO stop the reaction at NO, similar to CO2-to-CO conversion. At higher potentials, a low barrier for N coupling with NO may lead to N2O formation.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-Performance Electrochemical NO Reduction into NH3 by MoS2 Nanosheet

Longcheng Zhang et al.

Summary: MoS2/GF nanosheet on graphite felt shows promising catalytic performance in electrochemical reduction of NO for NH3 production, offering a potential environmentally friendly and efficient approach for nitrogen cycle restoration.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹
Article Chemistry, Physical

High-efficiency electrohydrogenation of nitric oxide to ammonia on a Ni2P nanoarray under ambient conditions

Ting Mou et al.

Summary: This study reports a Ni2P/CP composite material as an efficient electrocatalyst for the highly selective hydrogenation of NO to NH3, with good electrochemical durability. Experimental and theoretical investigations demonstrate its activity and selectivity in the NO reduction reaction.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-performance NH3 production via NO electroreduction over a NiO nanosheet array

Pengyu Liu et al.

Summary: A NiO nanosheet array on titanium mesh has been proposed as an efficient catalyst for electrocatalytic NO reduction, achieving high selectivity for NH3 production. Experimental and theoretical calculations reveal the high faradaic efficiency and NH3 yield of the catalyst.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Cobalt phosphide nanorings towards efficient electrocatalytic nitrate reduction to ammonia

Qing-Ling Hong et al.

Summary: High-quality CoP nanorings (CoP NRs) are easily achieved by phosphorating treatment of CoOOH nanorings, showing high activity towards hydrogen evolution reaction and nitrate electrocatalytic reduction reaction due to coordinately unsaturated active sites, high surface area, and mass transfer pathways. The CoP NRs can achieve 97.1% faradaic efficiency towards NO3--to-NH3 conversion and yield 30.1 mg h(-1) mg(cat)(-1) NH3 at -0.5 V potential.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹
Review Chemistry, Multidisciplinary

Emerging two-dimensional nanomaterials for electrochemical nitrogen reduction

Yingping Pang et al.

Summary: This article focuses on the electrochemical nitrogen reduction reaction (NRR) using two-dimensional (2D) nanomaterials as electrocatalysts, aiming to promote the sustainable production of NH3. The key metrics pursued in NRR, including the superior selectivity, activity, and stability of electrocatalysts, are highlighted in the study.

CHEMICAL SOCIETY REVIEWS (2021)

添加到收藏夹
Article Chemistry, Applied

La-doped TiO2 nanorods toward boosted electrocatalytic N2-to-NH3 conversion at ambient conditions

Li Li et al.

Summary: The development of La-doped TiO2 nanorods as an efficient NRR electrocatalyst for ambient NH3 synthesis has resulted in high NH3 yield and Faradaic efficiency, outperforming previous La- and Ti-based catalysts.

CHINESE JOURNAL OF CATALYSIS (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Boosting NH3 production from nitrate electroreduction via electronic structure engineering of Fe3C nanoflakes

Yuanyuan Wang et al.

Summary: This study demonstrates that N-doped carbon nanosheets supported Fe3C nanoflakes exhibit excellent NO3RR performance, mainly due to their optimized electronic structures that enhance nitrate adsorption and reaction kinetics. Mechanistic investigations reveal a reaction pathway of NO3- -> NO2- -> NH3.

GREEN CHEMISTRY (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-efficiency nitrate electroreduction to ammonia on electrodeposited cobalt-phosphorus alloy film

Zerong Li et al.

Summary: The study demonstrated the use of a Ti plate supported cobalt-phosphorus alloy film as a highly active and selective electrocatalyst for the conversion of nitrate to ammonia. The catalyst showed high NH3 yield rate, Faradaic efficiency, and durability under experimental conditions.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

Solar-driven electrochemical synthesis of ammonia using nitrate with 11% solar-to-fuel efficiency at ambient conditions

Nishithan C. Kani et al.

Summary: Ammonia is a crucial commodity chemical used in various industries, with traditional manufacturing processes consuming significant energy and emitting greenhouse gases. Solar-driven electrochemical synthesis of ammonia using nitrates presents a sustainable pathway for producing renewable fuels.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-efficiency electrochemical nitrite reduction to ammonium using a Cu3P nanowire array under ambient conditions

Jie Liang et al.

Summary: The study introduces a Cu3P nanowire array supported on copper foam as an efficient electrocatalyst for nitrite-to-ammonium conversion in neutral media. This catalyst demonstrates high ammonium yield rates, Faradaic efficiencies, and stability.

GREEN CHEMISTRY (2021)

添加到收藏夹
Article Chemistry, Physical

Alkylthiol surface engineering: an effective strategy toward enhanced electrocatalytic N2-to-NH3 fixation by a CoP nanoarray

Zhaobai Du et al.

Summary: Surface engineering of a CoP nanoarray supported on a titanium mesh using hydrophobic octadecanethiol enhances the electrocatalytic activity for N-2-to-NH3 conversion. This strategy improves NH3 yield and FE while maintaining stability and durability, showing promising potential for renewable electricity storage.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

CuS concave polyhedral superstructures enabled efficient N2 electroreduction to NH3 at ambient conditions

Shaoxiong Li et al.

Summary: CuS-CPSs have emerged as efficient electrocatalysts for artificial NH3 production, showing excellent selectivity and stability, with the best performance achieved at -0.15 V vs. reversible hydrogen electrode.

INORGANIC CHEMISTRY FRONTIERS (2021)

添加到收藏夹
Review Chemistry, Multidisciplinary

Nitrate electroreduction: mechanism insight, in situ characterization, performance evaluation, and challenges

Yuting Wang et al.

Summary: Excessive nitrate ions in the environment pose a significant threat to human health by disrupting the natural nitrogen cycle. Nitrate electroreduction, utilizing green electrons as reductants, shows promise due to its ability to operate under ambient conditions. Understanding the nitrate reaction mechanism is crucial for designing efficient electrocatalysts for selective nitrate reduction.

CHEMICAL SOCIETY REVIEWS (2021)

添加到收藏夹
Article Chemistry, Multidisciplinary

From the Birkeland-Eyde process towards energy-efficient plasma-based NOX synthesis: a techno-economic analysis

Kevin H. R. Rouwenhorst et al.

Summary: Plasma-based NOX synthesis via the Birkeland-Eyde process was one of the early industrial nitrogen fixation methods, but it never dominated the field due to the invention of the Haber-Bosch process. However, recent interest in plasma technology for nitrogen fixation has resurged with the availability of low cost, renewable electricity. Energy consumption for NOX synthesis with plasma technology is currently competitive with the commercial process, but further optimization is needed to achieve full competitiveness through effective plasma-catalyst coupling.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹
Article Chemistry, Physical

Efficient nitric oxide reduction to ammonia on a metal-free electrocatalyst

Qian Wu et al.

Summary: The study proposes a metal-free electrocatalyst, P atom doped single-layer C2N, for the direct electroreduction of NO to NH3 based on first-principles calculations. The microkinetic modeling analysis indicates that the turnover frequency of NO reduction to NH3 on the catalyst is as high as 8.9 x 10(5) per s per site at 400 K, demonstrating an ultra-fast reaction rate and offering a potential alternative avenue for ammonia synthesis.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

添加到收藏夹
Review Chemistry, Multidisciplinary

Recent progress in electrochemical synthesis of ammonia from nitrogen: strategies to improve the catalytic activity and selectivity

Bing Yang et al.

Summary: The modern ammonia synthesis industry established by Haber-Bosch in 1913 has changed the history of food production but its reliance on fossil fuels brings significant energy consumption and CO2 emissions. Electrochemical ammonia synthesis, as a green and sustainable alternative, has the potential to reduce fossil fuel consumption and CO2 emissions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹
Article Nanoscience & Nanotechnology

Two-dimensional (2D)/2D Interface Engineering of a MoS2/C3N4 Heterostructure for Promoted Electrocatalytic Nitrogen Fixation

Ke Chu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Rare Earth Single-Atom Catalysts for Nitrogen and Carbon Dioxide Reduction

Jieyuan Liu et al.

ACS NANO (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Unveiling the Activity Origin of a Copper-based Electrocatalyst for Selective Nitrate Reduction to Ammonia

Yuting Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Enhanced Nitrate-to-Ammonia Activity on Copper-Nickel Alloys via Tuning of Intermediate Adsorption

Yuhang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹
Article Chemistry, Physical

FeOOH quantum dots decorated graphene sheet: An efficient electrocatalyst for ambient N2 reduction

Xiaojuan Zhu et al.

NANO RESEARCH (2020)

添加到收藏夹
Review Chemistry, Multidisciplinary

Amorphous Catalysts and Electrochemical Water Splitting: An Untold Story of Harmony

Sengeni Anantharaj et al.

SMALL (2020)

添加到收藏夹
Article Chemistry, Physical

Boosting Selective Nitrate Electroreduction to Ammonium by Constructing Oxygen Vacancies in TiO2

Ranran Jia et al.

ACS CATALYSIS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Direct Electrochemical Ammonia Synthesis from Nitric Oxide

Jun Long et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

A Spectroscopic Study of Electrochemical Nitrogen and Nitrate Reduction on Rhodium Surfaces

Yao Yao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Graphdiyne Interface Engineering: Highly Active and Selective Ammonia Synthesis

Yan Fang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹
Review Chemistry, Multidisciplinary

Recent Advances and Challenges of Electrocatalytic N2 Reduction to Ammonia

Geletu Qing et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

CoS2 Nanoparticles-Embedded N-Doped Carbon Nanobox Derived from ZIF-67 for Electrocatalytic N2-to-NH3 Fixation under Ambient Conditions

Peipei Wei et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

添加到收藏夹
Review Chemistry, Physical

Rational Catalyst Design for N2 Reduction under Ambient Conditions: Strategies toward Enhanced Conversion Efficiency

Lei Shi et al.

ACS CATALYSIS (2020)

添加到收藏夹
Article Chemistry, Physical

Co3(hexahydroxytriphenylene)2: A conductive metal-organic framework for ambient electrocatalytic N2 reduction to NH3

Wei Xiong et al.

NANO RESEARCH (2020)

添加到收藏夹
Article Energy & Fuels

Electrochemical reduction of nitrate to ammonia via direct eight-electron transfer using a copper-molecular solid catalyst

Gao-Feng Chen et al.

NATURE ENERGY (2020)

添加到收藏夹
Article Chemistry, Physical

Electrocatalytic N2 reduction to NH3 with high Faradaic efficiency enabled by vanadium phosphide nanoparticle on V foil

Peipei Wei et al.

NANO RESEARCH (2020)

添加到收藏夹
Article Chemistry, Physical

Unveiling Electrode-Electrolyte Design-Based NO Reduction for NH3 Synthesis

DongYeon Kim et al.

ACS ENERGY LETTERS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Enhanced electrocatalytic N2-to-NH3 fixation by ZrS2 nanofibers with a sulfur vacancy

Tong Xu et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹
Article Chemistry, Physical

Enabling electrochemical conversion of N2 to NH3 under ambient conditions by a CoP3 nanoneedle array

Jiajia Gao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Unusual electrochemical N2 reduction activity in an earth-abundant iron catalyst via phosphorous modulation

Xiaojuan Zhu et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Highly efficient N2 fixation catalysts: transition-metal carbides M2C (MXenes)

Shuo Wang et al.

NANOSCALE (2020)

添加到收藏夹
Article Chemistry, Physical

Sn dendrites for electrocatalytic N2reduction to NH3under ambient conditions

Xu Lv et al.

SUSTAINABLE ENERGY & FUELS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Cu3P nanoparticle-reduced graphene oxide hybrid: an efficient electrocatalyst to realize N2-to-NH3conversion under ambient conditions

Runbo Zhao et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Bi nanodendrites for efficient electrocatalytic N2 fixation to NH3 under ambient conditions

Fengyi Wang et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

P-Doped graphene toward enhanced electrocatalytic N2 reduction

Tongwei Wu et al.

CHEMICAL COMMUNICATIONS (2020)

添加到收藏夹
Review Chemistry, Physical

Aqueous electrocatalytic N2 reduction for ambient NH3 synthesis: recent advances in catalyst development and performance improvement

Xiaojuan Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

添加到收藏夹
Article Chemistry, Multidisciplinary

Single-Boron Catalysts for Nitrogen Reduction Reaction

Chuangwei Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹
Review Materials Science, Multidisciplinary

Heterogeneous electrocatalysts design for nitrogen reduction reaction under ambient conditions

Yuchi Wan et al.

MATERIALS TODAY (2019)

添加到收藏夹
Article Chemistry, Physical

Mn3O4 nanoparticles@reduced graphene oxide composite: An efficient electrocatalyst for artificial N2 fixation to NH3 at ambient conditions

Hong Huang et al.

NANO RESEARCH (2019)

添加到收藏夹
Article Chemistry, Physical

Hexagonal boron nitride nanosheet for effective ambient N2 fixation to NH3

Ya Zhang et al.

NANO RESEARCH (2019)

添加到收藏夹
Article Multidisciplinary Sciences

Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis

Pengzuo Chen et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2019)

添加到收藏夹
Article Chemistry, Physical

Two-Dimensional Mosaic Bismuth Nanosheets for Highly Selective Ambient Electrocatalytic Nitrogen Reduction

Laiquan Li et al.

ACS CATALYSIS (2019)

添加到收藏夹
Article Chemistry, Physical

Boron Nanosheet: An Elemental Two-Dimensional (2D) Material for Ambient Electrocatalytic N2-to-NH3 Fixation in Neutral Media

Xiaoxue Zhang et al.

ACS CATALYSIS (2019)

添加到收藏夹
Article Nanoscience & Nanotechnology

Cr3C2 Nanoparticle-Embedded Carbon Nanofiber for Artificial Synthesis of NH3 through N2 Fixation under Ambient Conditions

Guangsen Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

添加到收藏夹
Article Chemistry, Physical

Copper Single Atoms Anchored in Porous Nitrogen-Doped Carbon as Efficient pH-Universal Catalysts for the Nitrogen Reduction Reaction

Wenjie Zang et al.

ACS CATALYSIS (2019)

添加到收藏夹
Article Nanoscience & Nanotechnology

Bioinspired Fe3C@C as Highly Efficient Electrocatalyst for Nitrogen Reduction Reaction under Ambient Conditions

Ming Peng et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Nanoporous Gold Embedded ZIF Composite for Enhanced Electrochemical Nitrogen Fixation

Yijie Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Greatly Improving Electrochemical N2 Reduction over TiO2 Nanoparticles by Iron Doping

Tongwei Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹
Article Chemistry, Physical

Elucidating the Mechanism of Electrochemical N2 Reduction at the Ru(0001) Electrode

Ebrahim Tayyebi et al.

ACS CATALYSIS (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation

Lili Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

A Biomass-Derived Carbon-Based Electrocatalyst for Efficient N2 Fixation to NH3 under Ambient Conditions

Hong Huang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹
Article Multidisciplinary Sciences

Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential

Mengfan Wang et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Boron-Doped TiO2 for Efficient Electrocatalytic N2 Fixation to NH3 at Ambient Conditions

Yuan Wang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

添加到收藏夹
Article Electrochemistry

Electrocatalytic N2 Fixation over Hollow VO2 Microspheres at Ambient Conditions

Rong Zhang et al.

CHEMELECTROCHEM (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-Performance N2-to-NH3 Conversion Electrocatalyzed by Mo2C Nanorod

Xiang Ren et al.

ACS CENTRAL SCIENCE (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction

Hengcong Tao et al.

CHEM (2019)

添加到收藏夹
Review Chemistry, Multidisciplinary

Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

Antonio Jose Martin et al.

CHEM (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Insights into defective TiO2 in electrocatalytic N2 reduction: combining theoretical and experimental studies

Li Yang et al.

NANOSCALE (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrocatalytic N2-to-NH3 conversion using oxygen-doped graphene: experimental and theoretical studies

Ting Wang et al.

CHEMICAL COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Physical

Improving the electrocatalytic N2 reduction activity of Pd nanoparticles through surface modification

Guorong Deng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹
Review Chemistry, Multidisciplinary

How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully

Cheng Tang et al.

CHEMICAL SOCIETY REVIEWS (2019)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

An Fe2O3 nanoparticle-reduced graphene oxide composite for ambient electrocatalytic N2 reduction to NH3

Jian Li et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Defect-rich fluorographene nanosheets for artificial N2 fixation under ambient conditions

Jinxiu Zhao et al.

CHEMICAL COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Physical

Electrospun TiC/C nanofibers for ambient electrocatalytic N2 reduction

Guangsen Yu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹
Review Chemistry, Multidisciplinary

Recent progress in the electrochemical ammonia synthesis under ambient conditions

Runbo Zhao et al.

ENERGYCHEM (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Enabling the electrocatalytic fixation of N2 to NH3 by C-doped TiO2 nanoparticles under ambient conditions

Kun Jia et al.

NANOSCALE ADVANCES (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Boosting electrocatalytic N2 reduction to NH3 on -FeOOH by fluorine doping

Xiaojuan Zhu et al.

CHEMICAL COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Physical

Ultrasmall V8C7 nanoparticles embedded in conductive carbon for efficient electrocatalytic N2 reduction toward ambient NH3 production

Jing Feng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Dendritic Cu: a high-efficiency electrocatalyst for N2 fixation to NH3 under ambient conditions

Chengbo Li et al.

CHEMICAL COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Ambient electrochemical N2-to-NH3 fixation enabled by Nb2O5 nanowire array

Wenhan Kong et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Metal-organic framework-derived shuttle-like V2O3/C for electrocatalytic N2 reduction under ambient conditions

Rong Zhang et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

添加到收藏夹
Review Chemistry, Physical

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Bryan H. R. Suryanto et al.

NATURE CATALYSIS (2019)

添加到收藏夹
Article Chemistry, Physical

Ambient electrohydrogenation of N2 for NH3 synthesis on non-metal boron phosphide nanoparticles: the critical role of P in boosting the catalytic activity

Xiaojuan Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Sulfur-doped graphene for efficient electrocatalytic N2-to-NH3 fixation

Li Xia et al.

CHEMICAL COMMUNICATIONS (2019)

添加到收藏夹
Article Chemistry, Multidisciplinary

Ambient Electrosynthesis of Ammonia: Electrode Porosity and Composition Engineering

Hong Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrochemical N2 fixation to NH3 under ambient conditions: Mo2N nanorod as a highly efficient and selective catalyst

Xiang Ren et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

High-Efficiency Electrosynthesis of Ammonia with High Selectivity under Ambient Conditions Enabled by VN Nanosheet Array

Rong Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Efficient Electrochemical N-2 Reduction to NH3 on MoN Nanosheets Array under Ambient Conditions

Ling Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

添加到收藏夹
Article Nanoscience & Nanotechnology

Enabling Effective Electrocatalytic N-2 Conversion to NH3 by the TiO2 Nanosheets Array under Ambient Conditions

Rong Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Nitrogen-free commercial carbon cloth with rich defects for electrocatalytic ammonia synthesis under ambient conditions

Wenyi Li et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Efficient and durable N-2 reduction electrocatalysis under ambient conditions: beta-FeOOH nanorods as a non-noble-metal catalyst

Xiaojuan Zhu et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Ag nanosheets for efficient electrocatalytic N-2 fixation to NH3 under ambient conditions

Hehan Huang et al.

CHEMICAL COMMUNICATIONS (2018)

添加到收藏夹
Article Chemistry, Multidisciplinary

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles

Xuan Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹
Article Chemistry, Physical

High-Performance Electrohydrogenation of N-2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions

Ya Zhang et al.

ACS CATALYSIS (2018)

添加到收藏夹
Article Chemistry, Physical

TiO2 nanoparticles-reduced graphene oxide hybrid: an efficient and durable electrocatalyst toward artificial N-2 fixation to NH3 under ambient conditions

Xiaoxue Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

添加到收藏夹
Review Chemistry, Physical

Single-Atom Catalysts: Synthetic Strategies and Electrochemical Applications

Yuanjun Chen et al.

JOULE (2018)

添加到收藏夹
Article Chemistry, Physical

Boron-Doped Graphene for Electrocatalytic N-2 Reduction

Xiaomin Yu et al.

JOULE (2018)

添加到收藏夹
Article Environmental Sciences

The electrochemical selective reduction of NO using CoSe2@CNTs hybrid

Hui Liu et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2017)

添加到收藏夹
Article Chemistry, Physical

Computational Predictions of Catalytic Activity of Zincblende (110) Surfaces of Metal Nitrides for Electrochemical Ammonia Synthesis

Younes Abghoui et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

添加到收藏夹
Review Multidisciplinary Sciences

Combining theory and experiment in electrocatalysis: Insights into materials design

Zhi Wei Seh et al.

SCIENCE (2017)

添加到收藏夹
Article Engineering, Environmental

Electrochemical nitrate reduction by using a novel Co3O4/Ti cathode

Liuhua Su et al.

WATER RESEARCH (2017)

添加到收藏夹
Article Chemistry, Multidisciplinary

Computational Screening of Rutile Oxides for Electrochemical Ammonia Formation

Arni B. Hoskuldsson et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrochemical Synthesis of NH3 at Low Temperature and Atmospheric Pressure Using a γ-Fe2O3 Catalyst

Jimin Kong et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹
Article Environmental Sciences

Is nitrogen the next carbon?

William Battye et al.

EARTHS FUTURE (2017)

添加到收藏夹
Article Chemistry, Applied

Onset potentials for different reaction mechanisms of nitrogen activation to ammonia on transition metal nitride electro-catalysts

Younes Abghoui et al.

CATALYSIS TODAY (2017)

添加到收藏夹
Article Chemistry, Multidisciplinary

Electrocatalytic Synthesis of Ammonia at Room Temperature and Atmospheric Pressure from Water and Nitrogen on a Carbon-Nanotube-Based Electrocatalyst

Shiming Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹
Article Chemistry, Physical

Electroreduction of N2 to Ammonia at Ambient Conditions on Mononitrides of Zr, Nb, Cr, and V: A DFT Guide for Experiments

Younes Abghoui et al.

ACS CATALYSIS (2016)

添加到收藏夹
Editorial Material Biochemistry & Molecular Biology

The nitrogen cycle

Lisa Y. Stein et al.

CURRENT BIOLOGY (2016)

添加到收藏夹
Article Chemistry, Multidisciplinary

Promising prospects for 2D d(2)-d(4) M3C2 transition metal carbides (MXenes) in N-2 capture and conversion into ammonia

Luis Miguel Azofra et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

添加到收藏夹
Article Respiratory System

Traffic-related air pollution and alveolar nitric oxide in southern California children

Sandrah P. Eckel et al.

EUROPEAN RESPIRATORY JOURNAL (2016)

添加到收藏夹
Article Multidisciplinary Sciences

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

Min Liu et al.

NATURE (2016)

添加到收藏夹
Article Chemistry, Physical

Nitrogen electrochemically reduced to ammonia with hematite: density-functional insights

Manh-Thuong Nguyen et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

添加到收藏夹
Article Chemistry, Physical

Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design

Younes Abghoui et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

添加到收藏夹
Article Chemistry, Inorganic & Nuclear

Mechanism of Nitric Acid Reduction and Kinetic Modelling

David Sicsic et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2014)

添加到收藏夹
Article Chemistry, Physical

Departures from the Adsorption Energy Scaling Relations for Metal Carbide Catalysts

Ronald Michalsky et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

添加到收藏夹
Article Chemistry, Multidisciplinary

The Haber-Bosch Process Revisited: On the Real Structure and Stability of Ammonia Iron under Working Conditions

Timur Kandemir et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹
Article Electrochemistry

On the kinetics of the nitrate reduction in concentrated nitric acid

Ronny Lange et al.

ELECTROCHEMISTRY COMMUNICATIONS (2013)

添加到收藏夹
Article Biology

Consequences of human modification of the global nitrogen cycle

Jan Willem Erisman et al.

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES (2013)

添加到收藏夹
Article Chemistry, Physical

A theoretical evaluation of possible transition metal electro-catalysts for N-2 reduction

Egill Skulason et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

添加到收藏夹
Review Multidisciplinary Sciences

The Evolution and Future of Earth's Nitrogen Cycle

Donald E. Canfield et al.

SCIENCE (2010)

添加到收藏夹
Article Chemistry, Applied

Transition metal phosphide hydroprocessing catalysts: A review

S. Ted Oyama et al.

CATALYSIS TODAY (2009)

添加到收藏夹
Review Chemistry, Multidisciplinary

Nitrogen Cycle Electrocatalysis

Victor Rosca et al.

CHEMICAL REVIEWS (2009)

添加到收藏夹
Article Geosciences, Multidisciplinary

How a century of ammonia synthesis changed the world

Jan Willem Erisman et al.

NATURE GEOSCIENCE (2008)

添加到收藏夹
Article Chemistry, Physical

Electrochemical and FTIRS characterisation of NO adlayers on cyanide-modified Pt(111) electrodes: the mechanism of nitric oxide electroreduction on Pt

Angel Cuesta et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2008)

添加到收藏夹
Article Chemistry, Physical

In situ surface-enhanced IR absorption spectroscopy on the adsorption and reduction of nitric oxide at ruthenium electrode

Yan-Gang Yan et al.

JOURNAL OF CATALYSIS (2007)

添加到收藏夹
Article Engineering, Biomedical

Diffusivity and solubility of nitric oxide in water and saline

IG Zacharia et al.

ANNALS OF BIOMEDICAL ENGINEERING (2005)

添加到收藏夹
Article Chemistry, Analytical

The influence of nitrate concentration and acidity on the electrocatalytic reduction of nitrate on platinum

MT de Groot et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2004)

添加到收藏夹
Review Environmental Sciences

Nitrogen cycles:: past, present, and future

JN Galloway et al.

BIOGEOCHEMISTRY (2004)

添加到收藏夹
Article Multidisciplinary Sciences

The reduction potential of nitric oxide (NO) and its importance to NO biochemistry

MD Bartberger et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2002)

添加到收藏夹
研讨会 海报 问题 讨论圈 基金 期刊 论文 科研社交 资讯集成 审稿人 关于我们 常见问题 移动App 隐私条款 使用条款
© Peeref 2019-2024. All rights reserved.