期刊
RSC ADVANCES
卷 6, 期 108, 页码 106435-106442出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra23504b
关键词
-
资金
- high-tech project of MOST (Ministry of Science and Technology of the People's Republic of China) [2014AA032802]
- Key Research Program of the Chinese Academy of Sciences [KFZD-SW-403]
A novel thermochromic WO3/VO2/WO3 sandwich structure was deliberately designed and deposited by a reactive magnetron sputtering technique. The double layer of WO3 not only functions as an antireflection (AR) layer to enhance the luminous transmittance (T-lum) of VO2, but also performs as a good protective layer for thermochromic VO2. Basically, the bottom WO3 layer functions as a buffer beneficial for the formation of the intermediate VO2 layer and serves as an AR layer while the intermediate VO2 layer with primary monoclinic phase acts as an automatic solar/heat control for energy saving. The top WO3 layer acts as another AR layer, and provides protection in a complex environment. An obvious increase in Tlum by 49% (from 37.2% to 55.4%) is found for VO2 films after introducing double-layer WO3 AR coating. The VO2 deposited on glass exhibits good thermochromism with an optical transition at 54.5 degrees C, which decreases to 52 degrees C in WO3/VO2/WO3 sandwich structure, and the hysteresis loop is sharper around the transition temperature, which may be ascribed to the strain and interfacial diffusion. In comparison with single-layer VO2, the durability in automatic solar/heat control of sandwich-structure VO2 films is improved nearly 4 times in high temperature and humidity conditions. This multilayer will open a new avenue for the design and integration of advanced thermochromic heterostructures with controllable functionalities for intelligent window and sensing system applications.
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