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Plasmonic polymer nanoantenna arrays for electrically tunable and electrode-free metasurfaces

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JOURNAL OF MATERIALS CHEMISTRY A
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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ta03383

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Electrically tunable and electrode-free metasurfaces can operate across the entire spectral range of the material, including the mid-infrared region, by using plasmonic polymer inverted nanoantenna arrays. The nanofabrication method presented in this study is suitable for various types of plasmonic polymer metasurfaces, including inverted arrays of nanoantennas. Inverted metasurfaces are of particular interest as they can work as electrodes themselves, enabling electrical control without the need for additional electrodes.
Electrically tunable metasurfaces and interrelated nanofabrication techniques are essential for metasurface-based optoelectronic applications. We present a nanofabrication method suitable for various types of plasmonic polymer metasurfaces including inverted arrays of nanoantennas. Inverted metasurfaces are of particular interest since the metasurface itself can work as an electrode due to its interconnected nature, which enables electrical control without adopting an additional electrode. In comparison with inverted nanodisk arrays that support relatively weak resonance features, we show that inverted nanorod arrays can possess stronger resonances, even comparable with those of nanorod arrays. The origin of plasmon resonances in inverted arrays is systematically investigated using finite-difference time-domain (FDTD) simulations. Further, we demonstrate electrically tunable electrode-free metasurface devices using polymer inverted nanorod arrays, which can operate in the full spectral range of the material including the mid-infrared region. Electrically tunable and electrode-free metasurfaces using plasmonic polymer inverted nanoantenna arrays can operate across the entire spectral range of the material, including the mid-infrared region.

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