4.7 Article

Versatile nicotinamide enabling dendrite-free and efficient deposition for aqueous Zn-I-2 batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Physical

Iodine conversion chemistry in aqueous batteries: Challenges, strategies, and perspectives

Lijing Yan et al.

Summary: This article provides a systematic summary of recent advances in aqueous iodine-based static batteries (AISBs). It discusses the fundamental physicochemical properties of iodine and its conversion chemistry, as well as the challenges and coping strategies. The article also explores the potential research opportunities and future directions in advancing AISBs.

ENERGY STORAGE MATERIALS (2023)

Article Chemistry, Multidisciplinary

pH-Triggered Molecular Switch Toward Texture-Regulated Zn Anode

Shao-Jian Zhang et al.

Summary: In this study, a dynamic Zn interface modulation based on the molecular switch strategy is utilized to solve the unstable Zn/electrolyte interface problem of Zn electrodes in aqueous media. This modulation is achieved by employing gamma-butyrolactone (GBL) in ZnCl2/H2O electrolyte. The dynamic molecular switch strategy enables high Zn reversibility and enhances the cycling performance of Zn||iodine batteries under high Zn depth of discharge (50%).

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

Organic pH Buffer for Dendrite-Free and Shuttle-Free Zn-I2 Batteries

Yanqiu Lyu et al.

Summary: A class of N-containing heterocyclic compounds acts as organic pH buffers in aqueous Zn-Iodine (I-2) batteries to mitigate issues such as Zn dendrites, hydrogen evolution reaction (HER), corrosion, and polyiodines shuttle. These compounds regulate electrolyte pH, inhibit HER and anode corrosion, and preferentially absorb on Zn metal, achieving non-dendritic Zn plating/stripping. The batteries with these buffers exhibit high Coulombic efficiency, long-term cycling stability, and improved conversion kinetics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Physical

A zincophilic interface coating for the suppression of dendrite growth in zinc anodes

Qingqing Ren et al.

Summary: In this study, the uncontrollable dendritic Zn deposition and associated interface mechanisms in aqueous rechargeable Zn batteries were investigated. Zn plating behaviors in different scales were clarified, and a dislocation-rich feature in Zn deposits near the interface was discovered. By constructing a (111) plane-oriented Au coating layer on Zn anodes (Au-Zn), the zincophilic interlayer was found to effectively control Zn deposition with suppressed crystalline defects and dendrites. Coin-type cells with Au-Zn electrodes exhibited lower overpotentials and higher stability compared to bare Zn electrodes (490 h vs 68 h). These findings provide important insights into material electrochemistry and offer guidance for future interfacial design for aqueous rechargeable Zn batteries.

NANO ENERGY (2023)

Article Chemistry, Physical

A high-capacity Sn metal anode for aqueous acidic batteries

Haozhe Zhang et al.

Summary: Aqueous acidic batteries are a good choice for renewable energy storage due to their safety, cost-effectiveness, environmental-friendliness, and high power capacity. However, the low voltage and energy density caused by inadequate metal anode materials hinder their practical adoption. In this study, an interfacial regulated Sn metal anode is proposed as a solution to this problem, demonstrating the potential for uniform deposition and alloying to suppress the critical issue of Sn metal shedding. The reversible Sn anode exhibits a high capacity of 442 mAh g-1 and is compatible with different cathodes, enabling the assembly of acidic batteries with sufficient output voltage, energy density, kinetics, and stability.
Article Chemistry, Physical

Perspective Ten concerns of Zn metal anode for rechargeable aqueous zinc batteries

Xiaoyu Yu et al.

Summary: Based on fair experiments, we propose ten critical concerns on ZMAs, including scientific concepts misunderstanding, non-scientific engineering factors affecting CE assessment, influence mechanisms of coating modifications, and limitations of characterization tools. We not only raise existing dilemmas but also provide solutions. This perspective aims to awaken research status on aqueous zinc batteries and provide constructive guidance for energy storage challenges.
Article Chemistry, Physical

Multifunctional porous carbon strategy assisting high-performance aqueous zinc-iodine battery

Lijing Yan et al.

Summary: The study proposes a strategy of using porous carbon to modify the zinc anode and immobilize the iodine active materials in order to address the performance degradation issues of aqueous zinc-iodine batteries. The optimized battery demonstrates satisfactory capacity retention and fast charging speed at high rates.

CARBON (2022)

Article Chemistry, Multidisciplinary

Tuning Zn-Ion Solvation Chemistry with Chelating Ligands toward Stable Aqueous Zn Anodes

Rongwei Meng et al.

Summary: Changing the solvation sheath is an effective strategy for stabilizing Zn-ion batteries, but key points related to the design remain unclear. This study proposes using stability constant as a universal standard to improve anode stability and achieves excellent stability of the Zn anode.

ADVANCED MATERIALS (2022)

Review Electrochemistry

Towards Understanding the Corrosion Behavior of Zinc-Metal Anode in Aqueous Systems: From Fundamentals to Strategies

Qian Li et al.

Summary: In this review, the challenges and solutions for the practical applications of rechargeable aqueous zinc-metal batteries (RAZMBs) were discussed. The focus was on mitigating the side reactions of zinc corrosion and hydrogen evolution at the electrode-electrolyte interface. The fundamental principles of corrosion thermodynamics and kinetics of zinc electrodes in aqueous media were elucidated, and recent optimization strategies targeting enhanced stability of zinc electrodes were reviewed. Future perspectives for the development of zinc anode applications were also provided.

BATTERIES & SUPERCAPS (2022)

Article Chemistry, Physical

Fundamentals and perspectives of electrolyte additives for aqueous zinc-ion batteries

Shan Guo et al.

Summary: Electrolyte additive is a key technology in energy storage, especially for aqueous zinc-ion batteries, but there is a lack of systematic research on its features and mechanisms. A comprehensive review on commonly used zinc-ion electrolyte additives is essential for further improvements in this field.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Mechanism for Zincophilic Sites on Zinc-Metal Anode Hosts in Aqueous Batteries

Fangxi Xie et al.

Summary: The bonding between zinc ions and zincophilic sites is revealed as the mechanism for suppressing zinc-dendrite formation in the ZMA host, leading to enhanced electrochemical performance. This study highlights the importance of nitrogen zincophilic sites in inhibiting zinc-dendrite growth.

ADVANCED ENERGY MATERIALS (2021)

Article Electrochemistry

In-situ constructing polyacrylamide interphase enables dendrite-free zinc anode in aqueous batteries

Xiaomin Zeng et al.

Summary: The study focuses on improving the performance of zinc anodes by constructing a polyacrylamide interphase, which enables homogeneous nucleation and high coulombic efficiency, leading to an extended lifespan of the battery.

ELECTROCHIMICA ACTA (2021)

Review Chemistry, Physical

Electrolyte Strategies toward Better Zinc-Ion Batteries

Cunxin Liu et al.

Summary: With the increasing demand for large-scale energy storage, high safety and low cost rechargeable zinc-ion batteries are considered as potential substitutes for lithium-ion batteries. However, fundamental issues hinder the development of zinc-based energy storage systems. The electrolyte plays a crucial role in ensuring the compatibility and cycling of battery components, and strategies to address issues such as cathode dissolution, zinc dendrites, corrosion, and hydrogen evolution are discussed.

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

Zinc dendrite growth and inhibition strategies

Y. Zuo et al.

Summary: Zinc is an ideal energy carrier with high energy density, low cost, and environmental friendliness, but the issue of zinc dendrite growth remains unresolved. Understanding the formation mechanism of zinc dendrites is necessary to guide inhibition strategies.

MATERIALS TODAY ENERGY (2021)

Review Chemistry, Physical

Undesired Reactions in Aqueous Rechargeable Zinc Ion Batteries

Vivek Verma et al.

Summary: Rechargeable zinc-ion batteries using aqueous electrolytes offer high safety, low cost, and fast charge/discharge rates, but also lead to undesired reactions that result in capacity fade and limited operational lifetimes.

ACS ENERGY LETTERS (2021)

Article Chemistry, Multidisciplinary

Amino Acid-Induced Interface Charge Engineering Enables Highly Reversible Zn Anode

Haotian Lu et al.

Summary: This research presents a new strategy of zinc-electrolyte interface charge engineering induced by amino acid additives, leading to highly reversible zinc plating/stripping with improved stability and uniformity of the zinc metal anode. Long-term stable cycling at high and ultra-high current densities has been demonstrated, highlighting the reliable self-adaptive feature of the zinc-electrolyte interface.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Stabilizing Zinc Anodes by Regulating the Electrical Double Layer with Saccharin Anions

Cong Huang et al.

Summary: The research shows that saccharin (Sac) as an electrolyte additive can regulate the electrical double layer (EDL) structure on the zinc anode, forming a unique solid electrolyte interphase (SEI) that effectively modulates zinc deposition behavior and prevents side reactions, thus improving battery performance.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Controllably Electrodepositing ZIF-8 Protective Layer for Highly Reversible Zinc Anode with Ultralong Lifespan

Xiaomin Zeng et al.

Summary: By utilizing controllable electrodeposition to construct a continuous and compact ZIF-8 protective layer, this study successfully inhibits dendrite growth and achieves an extended cycle life of over 5000 cycles in aqueous zinc-ion batteries.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Chemistry, Physical

Dual-Function Electrolyte Additive for Highly Reversible Zn Anode

Shao-Jian Zhang et al.

Summary: The study introduces a simple method using ethylene diamine tetraacetic acid tetrasodium salt (Na(4)EDTA) to suppress the poor reversibility of the Zn anode in aqueous Zn-ion batteries, effectively inhibiting dendrite growth and hydrogen evolution. Additionally, the added EDTA promotes desolvation of Zn, prolonging the electrode lifespan.

ADVANCED ENERGY MATERIALS (2021)

Article Energy & Fuels

Realizing high zinc reversibility in rechargeable batteries

Lin Ma et al.

NATURE ENERGY (2020)

Review Chemistry, Multidisciplinary

Fundamentals and perspectives in developing zinc-ion battery electrolytes: a comprehensive review

Tengsheng Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Dendrites in Zn-Based Batteries

Qi Yang et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase

Zhiming Zhao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Metallurgy & Metallurgical Engineering

A review of organic additives in zinc electrodeposition process (performance and evaluation)

Nabil Sorour et al.

HYDROMETALLURGY (2017)

Review Electrochemistry

Electrocrystallization Nucleation and growth phenomena

E Budevski et al.

ELECTROCHIMICA ACTA (2000)