期刊
RSC ADVANCES
卷 6, 期 83, 页码 80226-80233出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra14493d
关键词
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资金
- National Natural Science Foundation of China [U1204503]
- Key projects of science and technology of Henan Educational Committee [14B150049, 2010A150014]
Various morphologies of Bi2WO6 including packed nanoplates, three dimensional (3D) hierarchical flower-like and clew-like microspheres were successfully synthesized through a simple hydrothermal route using L-lysine as a structure-directing agent. It was found that the morphological modulation of the as-prepared products could be easily realized by adjusting the solution pH values of the precursors. On the basis of a series of time-dependent experiments, the possible mechanisms for the formation of three different structures were proposed. The photocatalytic activities of the different morphologies of Bi2WO6 were evaluated by photodegradation of Rhodamine B (RhB) solution under visible light irradiation (lambda > 400 nm). In comparison with clew-like and plate-like Bi2WO6 structures, Bi2WO6 with a hierarchical flower-like architecture exhibited the highest visible-light-photocatalytic activity. The enhanced photocatalytic activity could be mainly ascribed to the unique structural features of flower-like microspheres with hierarchical architectures.
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