期刊
RSC ADVANCES
卷 6, 期 13, 页码 10670-10676出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra25600c
关键词
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资金
- National Nature Science Foundation of China [51501129, 51371126]
- Science and Technology supporting program in Tianjin [14ZCZDGX00007]
- Self-Create Program of Science and Technology Plan in Tianjin Binhai New Area [2012-BK120024]
Cu-Ag-based highly conductive patterns were drawn directly on a flexible substrate using a roller pen filled with Cu-Ag NPs ink. The particle packing density is important for the pattern's conductivity. First, the addition of smaller Cu NPs (similar to 6.5 nm) between the larger Ag particles (similar to 16.5 nm) improves the particle packing density by filling the pores, which can help improve conductivity at lower temperatures. Furthermore, combination of temperature and stress by hot sintering & hot-pressure sintering makes the residual pore space decrease and improves the conductivity of the patterns. Finally, compared to bulk Cu wire (1.72 mu Omega cm), the resistivity of the Cu-Ag patterns sintered at 160 degrees C is reduced to 6.2 +/- 0.4 mu Omega cm, which is acceptable for conductive patterns. Samples with a decorative logo drawn by the Cu-Ag NPs exhibited excellent conductive performance and mechanical integrity.
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