期刊
RSC ADVANCES
卷 6, 期 2, 页码 1627-1636出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra22444f
关键词
-
资金
- Lebanese University
- University of Limoges
- AZM
- SAADE association
- PCSI programs in AUF
- PHC Cedre (PHOSFER project)
Zero Valent Iron (ZVI) is widely investigated in water treatment processes; the removal of contaminants may take place at the surface of ZVI or at the surface of its oxidation byproducts that have flaked off into the bulk solution. In this work, iron byproducts were synthetized under different aeration conditions (4 or 8 mg O-2 per L) and aging times (40 h or 6 days). The prepared iron oxidation byproducts were characterized using Xray diffraction (XRD), Fourier transform infrared (FTIR), Raman spectroscopy, zeta potential, BET surface area, and particle size analyses. XRD analysis showed that the prepared iron oxidation byproducts were composed mostly of lepidocrocite, maghemite, and magnetite. These flaked off iron oxidation byproducts were used alone (without ZVI) to remove phosphate. Equilibrium and kinetic studies were conducted to determine the sorption capacities and the rate of phosphate ion uptake at various pH values by the prepared byproducts. The experimental data showed that phosphate sorption adhered to a pseudo second order kinetic model and the maximum sorption capacity was determined at 2.5 mg P per g. Phosphate removal capacities of synthetic pure iron oxides and oxy-hydroxides were also determined. Raman and FTIR spectroscopy showed that phosphate was retained by inner sphere complexation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据