4.6 Article

A thermo-responsive dual-crosslinked hydrogel with ultrahigh mechanical strength

期刊

RSC ADVANCES
卷 6, 期 68, 页码 63848-63854

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra12278g

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资金

  1. National Nature Science Foundation of China [51473007, 21104040]
  2. State Key Laboratory of Solid Lubrication of Lanzhou Institute of Chemical Physics [LSL-1501]
  3. Innovative research team of polymeric functional film of Beijing technology and business university [19008001071]

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A tough poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAM-co-AA)) hydrogel has been engineered by a hybrid covalently cross-linked P(NIPAM-co-AA) and an ionic (COO)(3)Fe(III) coordinated network. The tough dual crosslinked hydrogel exhibited similar to 6 MPa of tensile strength, 69.8 MPa of compressive strength and 330% of elongation at break. The temperature sensitive swelling behavior depended significantly on the hydrogel architecture.

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