期刊
RSC ADVANCES
卷 6, 期 78, 页码 74845-74858出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra15002k
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资金
- Ministry of Science and Technology of the Republic of China [MOST 103-2113-M-003-008-MY3]
- National Taiwan Normal University [103-07-C]
- Instrumentation Centre at National Taiwan Normal University
Copper catalyzed C-terminal and N-terminal attack of 2-alkynylanilines to 2-iodobenzamides afforded isoindolinones and 1,2-disubstituted indoles, respectively. Further, the isoindolinone derivatives were converted to spiro fused isoindolinone-indolines utilizing a halonium ion mediated strategy using NBS/TCC in the presence of acetic anhydride. Also, the ortho effect of the amide group in 2-iodobenzamide has been successfully applied for the synthesis of 1,2-disubstituted indoles.
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