期刊
RSC ADVANCES
卷 6, 期 55, 页码 49941-49953出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra06417e
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资金
- P.O.R. Sicilia, Misura 3.15 Quota Regionale
- MIUR [PONa3_00053]
New pH-responsive nanosponges were obtained by reacting four different polyaminocyclodextrins with heptakis-(6-bromo)-(6-deoxy)-beta-cyclodextrin. The materials obtained were characterized by various techniques (FT-IR, potentiometric titration, differential scanning calorimetry (DSC), porosimetry (BET), C-13 {H-1} CP-MAS NMR). Their adsorption abilities at different pH values were verified towards a suitable set of model guests, and seem mainly controlled by electrostatic interactions, as a function of the protonation/charge status of the polymer matrix. By contrast, data positively point out a lesser importance assumed by the induced-fit effect, important in affecting the formation of host-guest complexes in solution. The frequency-switched Lee-Goldburg (FSLG) heteronuclear correlation solid-state NMR technique was exploited in order to assess the possible location of the guests within the polymer matrix.
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