4.6 Article

Smectic liquid crystal polymers as a template for ultrathin CaCO3 nanolayers

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RSC ADVANCES
卷 6, 期 17, 页码 13953-13956

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra27752c

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  1. China Scholarship Council (CSC)
  2. VICI grant from the Netherlands Organization of Scientific Research
  3. Dutch Polymer Institute (DPI) [742, 776]

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The poly(aspartic acid) (pAsp) assisted infiltration of a nanoporous smectic liquid crystalline network with CaCO3 yields only similar to 1 nm thick crystalline nanolayers. This bioinspired strategy opens the way to new functional materials based on solution-grown quasi 2D crystals of only a few unit cells thick.

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