期刊
RSC ADVANCES
卷 6, 期 45, 页码 38887-38896出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra01053a
关键词
-
资金
- Research Fund for the Doctoral Program of Higher Education [20136102110049]
In this paper, a hyperbranched silsesquioxane polymer grafted graphene oxide (HPP-GO) was fabricated successfully. Hexamethylenediamine was firstly grafted onto the graphene oxide sheets. Then chloropropyl silsesquioxane and hexamethylenediamine were repeatedly grafted onto the hexamethylenediamine coated graphene oxide, which was confirmed by X-ray photoelectron spectroscopy, Fourier-transform infrared spectra, X-ray diffraction and transmission electron spectroscopy. Subsequently, the HPP-GO was incorporated into dicyclopentadiene bisphenol dicyanate ester (DCPDCE) to prepare composites. The effects of HPP-GO on the mechanical, dynamic mechanical, dielectric and thermal properties of DCPDCE resin were investigated systematically. Results show that the appropriate content of HPP-GO can enhance the mechanical properties including impact and flexural strengths of DCPDCE resin. When HPP-GO content is 0.6 wt%, the corresponding composite exhibits higher storage modulus, glass transition temperature and onset degradation temperature values than pure DCPDCE resin. In addition, the dielectric constant and loss of HPP-GO/DCPDCE composites are decreased with the increasing content of HPP-GO. These attractive properties of HPP-GO/DCPDCE composites suggest that the method proposed herein is effective to prepare high-performance graphene oxide/polymer composites.
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