期刊
RSC ADVANCES
卷 6, 期 75, 页码 71151-71155出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra18073f
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资金
- Russian Science Foundation [14-13-00296]
- Russian Science Foundation [14-13-00296] Funding Source: Russian Science Foundation
The 1,3-dipolar cycloaddition of azomethine ylides to fullerene C-60 was utilized to perform the synthesis of spiropyran-containing photochromic pyrrolidinofullerenes. It was found that photochromism is observed only for the hybrid compound containing an NO2 group in the pyran moiety, whereas the pyrrolidinofullerenes with Cl or F atoms in the spiropyran moiety do not possess photochromism. The photochromic fullerene hybrid is characterized by lower light sensitivity and photodegradation parameters compared to the initial spiropyrans, which can be attributed to reabsorption of activating radiation.
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