期刊
RSC ADVANCES
卷 6, 期 4, 页码 2611-2623出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra22540j
关键词
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资金
- CONICYT-FONDECYT [1140528]
- Fondecyt [3130483, 3150033, PFB-27]
- Red Doctoral REDOC.CTA, MINEDUC project [UCO1202]
Commercial carbon nanotubes (CNT), oxidized CNT (CNTox) and activated carbon (AC) were used as supports to prepare Ni/C catalysts with a nominal loading of 15 wt%. In addition, xNi/CNT catalysts with loadings of x: 10, 12, 15, 17, 20 wt% were prepared. The catalysts were characterized by N-2 physisorption, temperature-programmed decomposition (TPD), potentiometric titration, H-2-temperature programmed reduction (TPR), CO chemisorption and X-ray photoelectron spectroscopy (XPS). The catalysts were evaluated for the conversion of guaiacol at 573 K and 5 MPa H-2 pressure for 4 h in a batch reactor. The activity of the xNi/CNT catalysts was related to Ni dispersion, while their selectivity was similar and favored the formation of hydrogenation products. The activity of 15Ni/CNT catalyst was higher than those of 15Ni/CNTox and 15Ni/AC catalysts. The higher activity of the 15Ni/CNT catalyst compared to 15Ni/AC catalyst was possibly due to their different morphologies, while the lower activity of the 15Ni/CNTox catalyst was attributed to the limiting effect of surface oxygen groups on the support. In addition, the higher acidity of the 15Ni/CNTox catalyst enhanced its hydrogenolysis and deoxygenation capacities.
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