期刊
NANOSCIENCE AND NANOTECHNOLOGY LETTERS
卷 8, 期 11, 页码 1007-1013出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/nnl.2016.2188
关键词
Pyrochlore; Soot; Oxygen Vacancy; Catalytic Oxidation
资金
- National Natural Science Foundation of China [21007019, 21277059]
- Shandong provincial key research project [2014GSF117039, 2015GSF117025]
- Shandong provincial natural science foundation, China [2014ZRB01268]
A series of Nd2Sn2-xMnxO7 (x = 0, 0.05, 0.10, 0.20, 0.30, 0.40) pyrochlore catalysts were prepared by co-precipitation and calcinations method. The as-synthesized products were characterized by XRD, FT-IR, H-2-TPR, N-2 Adsorption-Desorption, DLS and PL techniques. Their catalytic activity for soot oxidation was investigated by TPO technique under both O-2 and NO+O-2 atmosphere. The incorporation of Mn strongly influences the textural properties, Sn-O bond strength, surface oxygen vacancy and redox properties of the catalysts, resulting in different catalytic performance of soot oxidation. All proychlore catalysts display soot oxidation activity with above 70% selectivity towards CO2 formation. The Mn doped solids exhibit higher activities than the undoped one in O-2, which may be related to the enhancement of reducibility and the increased surface oxygen vacancies. The presence of NO in the gas phase significantly enhanced the soot oxidation activity with ignition temperature decreased to about 350 degrees C, which is due to the promotion effect of NO2.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据