期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 12, 页码 4473-4477出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01925g
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资金
- Milan University
- Erasmus+ Programme
An improved hydrogenation of nitroarenes using nano-structured iron-and cobalt-based catalysts is presented. Modifications of the heterogeneous catalysts by N-doped graphene-flakes are crucial for the success of selective reductions. The use of polar solvents and basic additives has a significant positive influence on the rate of reduction of nitroarenes. This allows performing non-noble metal-catalysed hydrogenations under very mild reaction conditions (e.g. 70 degrees C and 20 bar). On the basis of the obtained catalytic results a heterolytic mechanism for the hydrogenation process is postulated, too.
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