期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 4, 页码 988-992出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01865j
关键词
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资金
- Japan Science and Technology Agency (JST), CREST
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC00112704]
A Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m(3) of H-2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. The pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.
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