期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 20, 页码 7461-7467出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy01266c
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资金
- EPSRC Standard Research Student (DTG) [EP/L505109/1]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo [2013/04813-6, 2015/11840-5, 2015/01491-3]
- Engineering and Physical Sciences Research Council [1366805] Funding Source: researchfish
Pd(ITMe)(2)(PhC CPh) acts as a highly reactive pre-catalyst in the unprecedented homogenous catalyzed diboration of terminal and internal alkynes, yielding a number of novel and known syn-1,2-diborylalkenes in a 100% stereoselective manner. DFT calculations suggest that a similar reaction pathway to that proposed for platinum phosphine analogues is followed, and that destabilization of key intermediates by the NHCs is vital to the overall success for the palladium-catalyzed B-B addition to alkynes.
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