期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 4, 页码 1214-1221出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy01195g
关键词
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资金
- National Natural Science Foundation of China [21003093]
- Key Program of the National Natural Science of China [21336008]
A highly efficient and selective oxidative condensation-hydrogenation process of renewable furfural with aliphatic alcohols catalyzed by metallic platinum in a one-pot reactor is developed. A series of supported platinum catalysts including Pt/FH, Pt/H, Pt/HT, Pt/Fe3O4, Pt/Al2O3 and Pt/ZrO2 are prepared and employed for the polarization of furfural in ethanol and n-propanol. It is found that, in the presence of Pt/FH and potassium carbonate, 93.9% conversion of furfural and 67.9% selectivity to furan-2-acrolein were obtained via oxidative condensation in the furfural-ethanol-O-2 (FEO) system, and 90.1% conversion of furfural and 90% selectivity to 3-(furan-2-yl-)-2-methylacrylaldehyde were obtained via oxidative condensation in the furfural-n-propanol-O-2 (FPO) system. Moreover, the oxygen in the FPO system is completely replaced by molecular hydrogen to allow the further conversion of 3-(furan-2-yl-)-2-methylacrylaldehyde, while the catalytic system was kept unchanged. During this process, 87.3% conversion of 3-(furan-2-yl-)-2-methylacrylaldehyde and 73.2% selectivity to 3-(furan-2-yl-)-2-methylpropanol were obtained via a hydrogenation reaction with the Pt/FH catalyst. Moreover, several common bases as promoters were investigated in detail. All the catalysts were characterized by XRD, TEM, SEM, TPD and BET methods to reveal their catalytic nature in the reaction.
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