期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 6, 期 19, 页码 7252-7258出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cy01066k
关键词
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资金
- Collaborative Innovation Center of Suzhou Nano Science and Technology
- National Basic Research Program of China (973 Program) [2012CB825803, 2013CB932702]
- National Natural Science Foundation of China [51422207, 51132006, 51572179, 21471106, 21501126]
- Specialized Research Fund for the Doctoral Program of Higher Education [20123201110018]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
We show the fabrication and photocatalytic properties of triazine-based carbon nitride (polytriazine imide, PTI). The obtained PTI, with higher crystallinity and a triazine structure unit, is sufficiently characterised by X-ray powder diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and solid state NMR. We demonstrate that PTI is an efficient photocatalyst for activation in air and water, by which, the total green cyclohexane selective oxidation (5.81% conversion and over 99.9% selectivity to cyclohexanone) can be realized only using air and water without any other oxidants, initiators and solvents.
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