Numerical simulation of CO2 separation from gas mixtures in membrane modules: Effect of chemical absorbent

In this study, a mathematical model is proposed for prediction of CO2 absorption from N-2/CO2 mixture by potassium threonate in a hollow-fiber membrane contactor (HFMC). CFD technique using numerical method of finite element was applied to solve the governing equations of model. Effect of different factors on CO2 absorption was analyzed and for investigation of absorbent type effect, functioning of potassium threonate was compared with diethanolamine (DEA). Axial and radial diffusion can be described with the two dimensional model established in this work. The obtained simulation results were compared with the reported experimental data to ensure accuracy of the model predictions. Comparison of model results with experimental data revealed that the developed model can well predict CO2 capture by potassium threonate in HFMCs. Increment of absorbent flow rate and concentration eventuate in enhancement of CO2 absorption. On the other hand, capture of CO2 will be reduced with increment of gas flow rate. According to the model results, potassium threonate can be considered as a more efficient absorbent as compared with DEA. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.