期刊
ADVANCED ENERGY MATERIALS
卷 7, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201602092
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资金
- National Natural Science Foundation of China [51372186]
- National Key Research and Development Program of China [2016YFA0202603]
Searching for a new material to build the next-generation rechargeable lithium-ion batteries (LIBs) with high electrochemical performance is urgently required. Owing to the low-cost, non-toxicity, and high-safety, the family of manganese oxide including the Na-Mn-O system is regarded as one of the most promising electrode materials for LIBs. Herein, a new strategy is carried out to prepare a highly porous and electrochemically active Na0.55Mn2O4 center dot 1.5H(2)O (SMOH) compound. As an anode material, the Na-Mn-O nanocrystal material dispersed within a carbon matrix manifests a high reversible capacity of 1015.5 mA h g(-1) at a current density of 0.1 A g(-1). Remarkably, a considerable capability of 546.8 mA h g(-1) remains even after 2000 discharge/charge cycles at the higher current density of 4 A g(-1), indicating a splendid cyclability. The exceptional electrochemical properties allow SMOH to be a promising anode material toward LIBs.
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