期刊
ACS CATALYSIS
卷 6, 期 4, 页码 2158-2162出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02878
关键词
propane dehydrogenation; heterogeneous catalysis; platinum; ZnO catalyst; hydrogen desorption; Lewis acid
资金
- National Science Foundation of China [21406162, 21506149, 21525626]
- Program for New Century Excellent Talents in University [NCET-10-0611]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars (MoE)
- Program of Introducing Talents of Discipline to Universities [B06006]
Compared to metallic platinum and chromium oxide, zinc oxide (ZnO) is an inexpensive and low-toxic alternative for the direct dehydrogenation of propane (PDH). However, besides the limited activity, conventional zinc-based catalysts suffer from serious deactivation, because of ZnO reduction and/or carbon deposition. Considering the high cost of platinum, reducing the amount of platinum in the catalyst is always desirable. This paper describes a catalyst comprising ZnO modified by trace platinum supported on Al2O3, where the Zn2+ species serve as active sites and platinum acts as a promoter. This catalyst contains less platinum than traditional platinum-based catalysts and is much more stable than conventional ZnO catalyst or commercial chromium-based systems during PDH. It is proposed that ZnO was promoted to a stronger Lewis acid by platinum; thus, easier C-H activation and accelerated H-2 desorption were achieved.
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