期刊
ACS CATALYSIS
卷 6, 期 6, 页码 3890-3894出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b00861
关键词
mechanochemistry; C-H bond activation; selective arylation; biaryls; ball milling
资金
- National Nature Science Foundation of China [21361130021]
- China Postdoctoral Science Foundation [2014M560494]
- Postdoctoral Science Foundation of Zhejiang Province
A fast and site-selective biaryl synthesis via dehydrogenative C-H/C-H arylation in a ball mill was developed. In this paper, both electron-deficient oximes and electron-rich anilides quickly and under mild conditions provided arylation with various arenes to give the biaryl products in high-level selectivity. Given the solventless mechanochemical conditions, the transformation obviated the use of large amounts of arene coupling partners as solvents and allowed utilization of more-complicated and more-expensive arenes as coupling partners, which may dramatically enhance the application prospect of the C-H/C-H arylation strategy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据