4.8 Article

Boronic Acids as Hydrogen Bond Donor Catalysts for Efficient Conversion of CO2 into Organic Carbonate in Water

期刊

ACS CATALYSIS
卷 6, 期 8, 页码 4871-4876

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01422

关键词

CO2 conversion; organic carbonate; boronic acid; hydrogen bond; water

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  1. Institute of Bioengineering and Nanotechnology (Biomedical Research Council, Agency for Science, Technology and Research (A*STAR), Singapore)

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Boronic acids together with onium salts provide highly efficient organocatalysts for the conversion of CO2 with epoxides into various cyclic carbonates in H2O under mild conditions. The combination of experimental and computational studies allows further understanding of this active organocatalytic system.

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