期刊
ACS CATALYSIS
卷 6, 期 8, 页码 5359-5365出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.6b01293
关键词
metal-organic framework; microporous materials; Co(II) complex; photocatalytic H-2 production; charge separation
资金
- NSFC [21371162, 51301159, 21521001]
- 973 program [2014CB931803]
- NSF of Anhui Province [1408085MB23]
- Recruitment Program of Global Youth Experts
- Fundamental Research Funds for the Central Universities [WK2060190026, WK2060190065]
The photodriven H-2 generation from water splitting, providing a high-performance energy source, has been recognized to be a promising pathway for solar energy conversion. However, the efficient charge separation for photocatalysts remains a critical issue. In this work, we have rationally encapsulated a Co(II) molecular photcatalyst, [Co-II(TPA)CI][CI] (TPA = tris(2-pyridylmethyl)-amine), inside the cages of a metal organic framework (MOF) photosensitizer, MIL-125-NH2, for visible-light-driven H-2 production. This noble-metal-free composite photocatalyst facilitates the photo induced charge transfer from MIL-125-NH2 to the Co(II) complex and greatly improves the spatial charge separation, thus significantly boosting the photocatalytic efficiency of H-2 production. In addition, MIL-125-NH2 behaves as a host matrix to achieve hetrogenization of the Co(II) complex, and thus, the composite can be well-recycled.
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